Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Hydrido complexes of calcium: a new family of molecular alkaline‐earth‐metal compounds
D Mukherjee, D Schuhknecht… - Angewandte Chemie …, 2018 - Wiley Online Library
The application of solid calcium hydride CaH2 has been mostly confined to its use as a
desiccant, although its catalytic activity has long been known. Since the first isolation of a …
desiccant, although its catalytic activity has long been known. Since the first isolation of a …
Organocalcium-mediated nucleophilic alkylation of benzene
The electrophilic aromatic substitution of a C–H bond of benzene is one of the archetypal
transformations of organic chemistry. In contrast, the electron-rich π-system of benzene is …
transformations of organic chemistry. In contrast, the electron-rich π-system of benzene is …
Imine hydrogenation with simple alkaline earth metal catalysts
H Bauer, M Alonso, C Färber, H Elsen, J Pahl… - Nature Catalysis, 2018 - nature.com
Hydrogenation of unsaturated bonds is dominated by transition metal catalysis. Compared
with transition metals, the use of other metals is less explored, especially so for the s-block …
with transition metals, the use of other metals is less explored, especially so for the s-block …
SuFEx Activation with Ca(NTf2)2: A Unified Strategy to Access Sulfamides, Sulfamates, and Sulfonamides from S(VI) Fluorides
S Mahapatra, CP Woroch, TW Butler, SN Carneiro… - Organic …, 2020 - ACS Publications
A method to activate sulfamoyl fluorides, fluorosulfates, and sulfonyl fluorides with calcium
triflimide and DABCO for SuFEx with amines is described. The reaction was applied to a …
triflimide and DABCO for SuFEx with amines is described. The reaction was applied to a …
Calcium Hydride Cation [CaH]+ Stabilized by an NNNN‐type Macrocyclic Ligand: A Selective Catalyst for Olefin Hydrogenation
D Schuhknecht, C Lhotzky, TP Spaniol… - Angewandte Chemie …, 2017 - Wiley Online Library
Reaction of dibenzyl calcium complex [Ca (Me4TACD)(CH2Ph) 2], containing the neutral
NNNN‐type macrocyclic ligand Me4TACD (Me4TACD= 1, 4, 7, 10‐tetramethyl‐1, 4, 7, 10 …
NNNN‐type macrocyclic ligand Me4TACD (Me4TACD= 1, 4, 7, 10‐tetramethyl‐1, 4, 7, 10 …
Heterobimetallic alkaline earth metal–metal bonding
J Mai, J Maurer, J Langer, S Harder - Nature Synthesis, 2024 - nature.com
Low-oxidation-state complexes of type (BDI) Mg–Mg (BDI)(BDI, β-diketiminate) show broad
reactivity, finding application as soluble, universal reducing agents, enriching the field of …
reactivity, finding application as soluble, universal reducing agents, enriching the field of …
Nucleophilic aromatic substitution at benzene with powerful strontium hydride and alkyl complexes
B Rösch, TX Gentner, H Elsen… - Angewandte Chemie …, 2019 - Wiley Online Library
Key to the isolation of the first alkyl strontium complex was the synthesis of a strontium
hydride complex that is stable towards ligand exchange reactions. This goal was achieved …
hydride complex that is stable towards ligand exchange reactions. This goal was achieved …
Super‐bulky penta‐arylcyclopentadienyl ligands: isolation of the full range of half‐sandwich heavy alkaline‐earth metal hydrides
X Shi, G Qin, Y Wang, L Zhao, Z Liu… - Angewandte …, 2019 - Wiley Online Library
Hydrogenolysis of the half‐sandwich penta‐arylcyclopentadienyl‐supported heavy alkaline‐
earth‐metal alkyl complexes (CpAr) Ae [CH (SiMe3) 2](S)(CpAr= C5Ar5, Ar= 3, 5‐iPr2 …
earth‐metal alkyl complexes (CpAr) Ae [CH (SiMe3) 2](S)(CpAr= C5Ar5, Ar= 3, 5‐iPr2 …
A simple route to calcium and strontium hydride clusters
B Maitland, M Wiesinger, J Langer… - Angewandte Chemie …, 2017 - Wiley Online Library
The first strontium hydride complex has been obtained by simply treating Sr [N (SiMe3) 2] 2
with PhSiH3 in the presence of PMDTA. The Sr complex Sr6H9 [N (SiMe3) 2] 3⋅(PMDTA) 3 …
with PhSiH3 in the presence of PMDTA. The Sr complex Sr6H9 [N (SiMe3) 2] 3⋅(PMDTA) 3 …