Oxidation of Organic Compounds Using Water as the Oxidant with H2 Liberation Catalyzed by Molecular Metal Complexes

S Kar, D Milstein - Accounts of chemical research, 2022 - ACS Publications
Conspectus Oxidation reactions of organic compounds play a central role in both industrial
chemical and material synthesis as well as in fine chemical and pharmaceutical synthesis …

Acceptorless dehydrogenative coupling reactions with alcohols over heterogeneous catalysts

SMAH Siddiki, T Toyao, K Shimizu - Green Chemistry, 2018 - pubs.rsc.org
Heterogeneous catalysis for the one-pot synthesis of added-value chemicals is a growing
area in green chemistry. Among various types of organic transformations that are accessible …

An enzyme-mimic single Fe-N3 atom catalyst for the oxidative synthesis of nitriles via C─C bond cleavage strategy

J Qin, B Han, X Liu, W Dai, Y Wang, H Luo, X Lu… - Science …, 2022 - science.org
The cleavage and functionalization of recalcitrant carbon─ carbon bonds is highly
challenging but represents a very powerful tool for value-added transformation of feedstock …

Dehydrogenative oxidation of alcohols in aqueous media catalyzed by a water-soluble dicationic iridium complex bearing a functional N-heterocyclic carbene ligand …

K Fujita, R Tamura, Y Tanaka, M Yoshida… - ACS …, 2017 - ACS Publications
A dicationic iridium complex bearing a bidentate ligand that comprises N-heterocyclic
carbene and α-hydroxypyridine moieties has been designed and synthesized. The complex …

Bis (methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic acids and aromatic ketones with O 2 under metal-and base-free conditions

KJ Liu, S Jiang, LH Lu, LL Tang, SS Tang, HS Tang… - Green …, 2018 - pubs.rsc.org
We describe an eco-friendly, practical and operationally simple procedure for the bis
(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic …

Acceptorless dehydrogenative coupling reactions by manganese pincer complexes

P Nad, A Mukherjee - Asian Journal of Organic Chemistry, 2021 - Wiley Online Library
Acceptorless dehydrogenative coupling reactions has emerged as one of the promising
technique in synthetic organic chemistry to construct carbon‐carbon and carbon‐heteroatom …

Unraveling the Electrooxidation Mechanism of 5-(Hydroxymethyl) furfural at a Molecular Level via Nickel-Based Two-Dimensional Metal–Organic Frameworks …

S Yang, Y Guo, P Zhao, H Jiang, H Shen, Z Chen… - ACS …, 2023 - ACS Publications
Electrochemical conversion of biomass can mitigate environmental issues while providing a
substitute for fossil products, yet it is challenging to construct efficient catalysts due to the …

Convergent production of 2, 5-furandicarboxylic acid from biomass and CO 2

H Zhou, H Xu, X Wang, Y Liu - Green Chemistry, 2019 - pubs.rsc.org
We report a rationally designed process for complete lignocellulose conversion and CO2
utilization to convergently produce 2, 5-furandicarboxylic acid (FDCA) that can be used in …

Selective Modular Synthesis of ortho-Substituted Phenols via Pd-Catalyzed Dehydrogenation–Coupling–Aromatization of Alcohols

G Zeng, L Shen, Q Zheng, T Tu - ACS Catalysis, 2023 - ACS Publications
Phenols are pivotal precursors and core motifs for various fine chemicals, bioactive
molecules, and functional materials, among which the site-selective syntheses of ortho …

Cobalt-catalyzed acceptorless dehydrogenation of alcohols to carboxylate salts and hydrogen

DR Pradhan, S Pattanaik, J Kishore… - Organic letters, 2020 - ACS Publications
The facile oxidation of alcohols to carboxylate salts and H2 is achieved using a simple and
readily accessible cobalt pincer catalyst (NNNHtBuCoBr2). The reaction follows an …