Nitroxide-mediated polymerization

J Nicolas, Y Guillaneuf, C Lefay, D Bertin… - Progress in Polymer …, 2013 - Elsevier
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

[HTML][HTML] Tailoring polymer dispersity and shape of molecular weight distributions: methods and applications

R Whitfield, NP Truong, D Messmer, K Parkatzidis… - Chemical …, 2019 - pubs.rsc.org
The width and shape of molecular weight distributions can significantly affect the properties
of polymeric materials and thus are key parameters to control. This mini-review aims to …

[HTML][HTML] Size-exclusion chromatography (SEC) of branched polymers and polysaccharides

M Gaborieau, P Castignolles - Analytical and bioanalytical chemistry, 2011 - Springer
Branched polymers are among the most important polymers, ranging from polyolefins to
polysaccharides. Branching plays a key role in the chain dynamics. It is thus very important …

Exploitation of the degenerative transfer mechanism in RAFT polymerization for synthesis of polymer of high livingness at full monomer conversion

G Gody, T Maschmeyer, PB Zetterlund… - Macromolecules, 2014 - ACS Publications
We report the synthesis by the reversible addition–fragmentation chain transfer process of
well-defined decablock polymers with a final dispersity as low as 1.15 and a fraction of living …

Asymmetric flow field-flow fractionation in the field of nanomedicine

M Wagner, S Holzschuh, A Traeger, A Fahr… - Analytical …, 2014 - ACS Publications
Asymmetric flow field-flow fractionation (AF4) is a widely used and versatile technique in the
family of field-flow fractionations, indicated by a rapidly increasing number of publications. It …

Thermo-Induced Self-Assembly of Responsive Poly(DMAEMA-b-DEGMA) Block Copolymers into Multi- and Unilamellar Vesicles

C Pietsch, U Mansfeld, C Guerrero-Sanchez… - …, 2012 - ACS Publications
A series of thermoresponsive diblock copolymers of poly [2-(dimethylamino) ethyl
methacrylate-block-di (ethyleneglycol) methyl ether methacrylate], poly (DMAEMA-b …

Polymer characterization by size-exclusion chromatography with multi-angle light scattering (SEC-MALS): a tutorial review

JB Matson, AQ Steele, JD Mase, MD Schulz - Polymer Chemistry, 2024 - pubs.rsc.org
This tutorial review presents the theory and application of SEC-MALS with minimal
equations and a focus on synthetic polymer characterization, serving as an entry point for …

Challenges of size-exclusion chromatography for the analysis of bottlebrush polymers

DJ Walsh, MA Wade, SA Rogers, D Guironnet - Macromolecules, 2020 - ACS Publications
The establishment of structure–function relationships requires the accurate characterization
of the materials being studied. For polymer science, size-exclusion chromatography (SEC) is …

The challenges of controlling polymer synthesis at the molecular and macromolecular level

K Hakobyan, J Xu, M Müllner - Polymer Chemistry, 2022 - pubs.rsc.org
Modern applications of polymers demand further elaboration of molecular-level structures as
well as control of various macro-level features. There have been significant advances …

Propagation Rate Coefficient for Radical Polymerization of N-Vinyl Pyrrolidone in Aqueous Solution Obtained by PLP−SEC

M Stach, I Lacik, D Chorvat Jr, M Buback… - …, 2008 - ACS Publications
Propagation rate coefficients, kp, of N-vinyl pyrrolidone (NVP) radical polymerization in
aqueous solution have been measured via the pulsed-laser polymerization-size exclusion …