Recent advances on metal–organic frameworks for deep purification of olefins

Y Jiang, W Yang, Y Zhang, L Wang… - Journal of Materials …, 2024 - pubs.rsc.org
The removal of trace impurities, such as alkynes and carbon dioxide, is critically important in
the production of high-purity light hydrocarbon olefins, which are essential for a variety of …

Recent advances in multifunctional reticular framework nanoparticles: a paradigm shift in materials science road to a structured future

M Chafiq, A Chaouiki, YG Ko - Nano-Micro Letters, 2023 - Springer
Porous organic frameworks (POFs) have become a highly sought-after research domain that
offers a promising avenue for developing cutting-edge nanostructured materials, both in …

Topological design of unprecedented metal‐organic frameworks featuring multiple anion functionalities and hierarchical porosity for benchmark acetylene separation

Y Zhang, W Sun, B Luan, J Li, D Luo… - Angewandte Chemie …, 2023 - Wiley Online Library
Separation of acetylene (C2H2) from carbon dioxide (CO2) or ethylene (C2H4) is industrially
important but still challenging so far. Herein, we developed two novel robust metal organic …

Incorporation of multiple supramolecular binding sites into a robust MOF for benchmark one-step ethylene purification

E Wu, XW Gu, D Liu, X Zhang, H Wu, W Zhou… - Nature …, 2023 - nature.com
One-step adsorption separation of C2H4 from ternary C2 hydrocarbon mixtures remains an
important and challenging goal for petrochemical industry. Current physisorbents either …

Construction of Negative Electrostatic Pore Environments in a Scalable, Stable and Low‐Cost Metal‐organic Framework for One‐Step Ethylene Purification from …

HM Wen, C Yu, M Liu, C Lin, B Zhao, H Wu… - Angewandte …, 2023 - Wiley Online Library
One‐step separation of C2H4 from ternary C2 mixtures by physisorbents remains a
challenge to combine excellent separation performance with high stability, low cost, and …

Cyclobutanedicarboxylate metal–organic frameworks as a platform for dramatic amplification of pore partition effect

W Wang, H Yang, Y Chen, X Bu… - Journal of the American …, 2023 - ACS Publications
Ultrafine tuning of MOF structures at subangstrom or picometer levels can help improve
separation selectivity for gases with subtle differences. However, for MOFs with a large …

Specific propyne trapping sites within a robust MOF for efficient propyne/propadiene separation with record propadiene productivity

Y Jiang, L Wang, J Hu, R Krishna, B Chen… - Advanced …, 2024 - Wiley Online Library
Separating propyne/propadiene to produce pure propadiene is extremely challenging in
industry due to their similar properties. Herein, a novel ZrF62− anion pillared cage‐like …

A customized hydrophobic porous shell for MOF-5

J Li, P Liu, Y Chen, J Zhou, J Li, J Yang… - Journal of the …, 2023 - ACS Publications
The susceptibility to moisture of metal–organic frameworks (MOFs) is a critical bottleneck for
their wider practical application. Constructing core–shell composites has been postulated as …

Pore engineering in cost-effective and stable Al-MOFs for efficient capture of the greenhouse gas SF6

Y Hu, L Wang, R Nan, N Xu, Y Jiang, D Wang… - Chemical Engineering …, 2023 - Elsevier
The capture and separation of the greenhouse gas sulfur hexafluoride (SF 6) from nitrogen
(N 2) holds significant potential for mitigating the greenhouse effect and yielding economic …

Leveraging Surface Chemistry and Pore Shape Engineering in a Metal‐Organic Framework for One‐Step Olefin Purification

X Lian, PX Liu, YC Yuan, JJ Pang, L Li… - Advanced Functional …, 2024 - Wiley Online Library
Purifying olefin from ternary paraffin/olefin/alkyne mixtures through a one‐step adsorption
process is extremely desirable. Herein, a stable zirconium (IV) metal‐organic framework with …