Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Single-molecule magnets (SMMs) are individual molecules that can function as nanoscale
magnetic particles. The [Mn12O12 (O2CR) 16 (H2O) 4](Mn12; R= Me, Et, etc.) family of …

The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

The reaction of MnCl2⊙ 4H2O (3 equiv), pyridine-2, 6-dimethanol (pdmH2)(10 equiv), and
NaN3 (10 equiv) in MeOH/MeCN (1: 2 v/v) with NMe4OH (1 equiv) gave [Mn25O18 (OH) 2 …

We report single-molecule-transistor measurements on devices incorporating magnetic
molecules. By studying the electron-tunneling spectrum as a function of magnetic field, we …

A brief survey is provided of single-molecule magnets (SMMs), or molecular nanomagnets.
The [Mn12O12 (O2CR) 16 (H2O) 4](Mn12; R= various) family of SMMs continues to be the …

Polynuclear 3d metal complexes are of interest for various reasons, one of which is the
possibility that they might exhibit high-spin (S) ground states and easy-axis-type magnetic …

The reaction between oxide-centered, triangular [MnIII3O (O2CR) 6 (py) 3](ClO4)(R= Me (1),
Et (2), Ph (3)) compounds and methyl 2-pyridyl ketone oxime (mpkoH) affords a new family …

This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …