Flexible metal–organic frameworks

A Schneemann, V Bon, I Schwedler… - Chemical Society …, 2014 - pubs.rsc.org
Advances in flexible and functional metal–organic frameworks (MOFs), also called soft
porous crystals, are reviewed by covering the literature of the five years period 2009–2013 …

Negative thermal expansion in framework structure materials

N Shi, Y Song, X Xing, J Chen - Coordination Chemistry Reviews, 2021 - Elsevier
Negative thermal expansion (NTE) is a counterintuitive physical phenomenon that the unit
cell volume of material usually contracts instead of expands upon heating. With two …

Responsive metal–organic frameworks and framework materials: under pressure, taking the heat, in the spotlight, with friends

FX Coudert - Chemistry of Materials, 2015 - ACS Publications
Recent years have seen a large increase of the research effort focused on framework
materials, including the nowadays-ubiquitous metal–organic frameworks but also dense …

Controlling flexibility of metal–organic frameworks

JP Zhang, HL Zhou, DD Zhou, PQ Liao… - National Science …, 2018 - academic.oup.com
Abstract Framework flexibility is one of the most important characteristics of metal–organic
frameworks (MOFs), which is not only interesting, but also useful for a variety of applications …

Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers

JP Zhang, PQ Liao, HL Zhou, RB Lin… - Chemical Society …, 2014 - pubs.rsc.org
X-Ray single-crystal diffraction has been the most straightforward and important technique in
structural determination of crystalline materials for understanding their structure–property …

The role of metal–organic frameworks in electronic sensors

LT Zhang, Y Zhou, ST Han - Angewandte Chemie, 2021 - Wiley Online Library
MOFs have a highly ordered self‐assembled nanostructure, high surface area, nanoporosity
with tunable size and shape, reliable host–guest interactions, and responsiveness to …

Flexibility in metal–organic frameworks: a fundamental understanding

SK Elsaidi, MH Mohamed, D Banerjee… - Coordination Chemistry …, 2018 - Elsevier
Expansion and contraction of structurally flexible Metal–Organic Frameworks (MOFs) or
Porous Coordination Polymers (PCPs) have been extensively studied from different …

Negative thermal expansion and associated anomalous physical properties: review of the lattice dynamics theoretical foundation

MT Dove, H Fang - Reports on Progress in Physics, 2016 - iopscience.iop.org
Negative thermal expansion (NTE) is the phenomenon in which materials shrink rather than
expand on heating. Although NTE had been previously observed in a few simple materials …

An artificial olfactory sensor based on flexible metal–organic frameworks for sensing VOCs

H Chen, Z You, X Wang, Q Qiu, Y Ying… - Chemical Engineering …, 2022 - Elsevier
An artificial olfactory sensor using seven flexible metal–organic frameworks (MOFs) was
designed to detect volatile organic compounds (VOCs) with high selectivity. Owing to its …

Massive Anisotropic Thermal Expansion and Thermo‐Responsive Breathing in Metal–Organic Frameworks Modulated by Linker Functionalization

S Henke, A Schneemann… - Advanced Functional …, 2013 - Wiley Online Library
Functionalized metal–organic frameworks (fu‐MOFs) of general formula [Zn2 (fu‐L) 2dabco]
n show unprecedentedly large uniaxial positive and negative thermal expansion (fu‐L …