Fluorinated gases (F-gases) are routinely employed as refrigerants, blowing agents, and
electrical insulators. These volatile compounds are potent greenhouse gases and …

The 2, 3-dihydrobenzofuran scaffold is widely found in natural products and biologically
active compounds. Herein, dearomatizing 2, 3-fluoroaroylation of benzofurans with aroyl …

Improving the stability of sensitive catalytic systems is an emerging research topic in the
catalysis field. However, the current design of heterogeneous catalysts mainly improves their …

Acyl fluorides are valuable intermediates in organic synthesis. They are increasingly
employed in peptide synthesis, in challenging esterification and amidation reactions or in …

We describe the development of a general palladium-catalyzed carbonylative method to
synthesize acyl fluorides from aryl, heteroaryl, alkyl, and functionalized organic halides …

Perfluoroalkyl substances (PFAS) are pervasive in the environment. The largest single use
material within the PFAS compound class is poly (tetrafluoroethylene)(PTFE), a robust and …

Acyl fluorides are versatile reagents in organic synthesis. However, there is no precedent to
employ acyl fluorides as acyl radical precursors. We herein report an N-heterocyclic …

We describe a novel reagent system to obtain acyl fluorides directly from three different
functional group precursors: carboxylic acids, aldehydes, or alcohols. The transformation is …

3, 3-Difluoro-1, 2-diphenylcyclopropene (CpFluor), a bench-stable fluorination reagent, has
been developed in the deoxyfluorination of carboxylic acids to afford various acyl fluorides …

The synthesis of acyl fluorides using the deoxofluorination reaction of carboxylic acids using
XtalFluor-E is described. This transformation, assisted by a catalytic amount of NaF, occurs …