The β− emitter, rhenium-188 (188Re), has long been recognized as an attractive candidate
for targeted cancer radionuclide therapy (TRNT). This transition metal shares chemical …

An air-and moisture-tolerant enantioselective hydrosilylation of N-phosphinyl imines
employing a chiral Re (V)− oxo complex as a catalyst is described. The chiral catalyst is a …

This work details an in-depth evaluation of an unprecedented mechanism for the
hydrosilylation of carbonyl compounds catalyzed by (PPh3) 2Re (O) 2I. The proposed …

Structural features of mononuclear octahedral dioxo complexes d 2-Re5+,[ReO2
(Lbi)(Lmono) 2] and [ReO2 (Lbi) 2] with mono-and bidentate ligands were considered. The …

Density functional calculations employing the B3LYP method and the LANL2DZ basis set
have been performed on several Re dioxo complexes of simple polyamines. An extended …

A sodium gadolinium phosphate crystal, Na3GdP2O8, has been synthesized by a high-
temperature solution reaction, and it exhibits a new structural family of the alkali-metal-rare …

Reactions of [nBu4N][Re (O) Cl4] 1 with an excess of the recently described
heterofunctionalized phosphane ligands 2-(diphenylphosphanyl)-N-(2-hydroxyethyl) …

The structural features of 34 mononuclear octahedral dioxocomplexes d 2-Re (V),[ReO2 (L)
4] with monodentate ligands L, containing one, two, or three types of donor atoms (N, C, P …

Two oxorhenium (V) complexes with bidentate phosphine ligands were synthesized and
isolated as [ReOCl3 (dppm)] 1 and [ReOCl3 (dppp)] 2 [where dppm= 1, 1-bis …

The new ligand 1, 2-bis (dicyclohexylphosphinite) ethane (L1) was prepared by reaction of
ethylenglycol with dicyclohexylphosphine in the presence of triethylamine. By treating this …