Palladium-catalyzed aerobic oxidation reactions have been the focus of industrial
application and extensive research efforts for nearly 60 years. A significant transition …

Selective aerobic oxidation of organic molecules is a fundamental and practical challenge in
modern chemistry. Effective solutions to this problem must overcome the intrinsic reactivity …

Many reactions are nowadays catalyzed by a transition metal, which not only accelerates the
reactions but allows, via its ligand (s), a fine control of the chemo-, regio-, and …

Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

Structurally, boronic acids are trivalent boron-containing organic compounds that possess
one alkyl substituent (ie, a C–B bond) and two hydroxyl groups to fill the remaining valences …

Gold nanoparticles (< 2 nm) stabilized by poly (N-vinyl-2-pyrrolidone)(Au: PVP NPs) were
prepared by reduction of AuCl4-with NaBH4 in the presence of PVP and characterized via …

The mechanism of the palladium-catalyzed homocoupling of arylboronic acids ArB (OH) 2
(Ar= 4-Z-C6H4 with Z= MeO, H, CN) in the presence of dioxygen, leading to symmetrical …

Die selektive aerobe Oxidation organischer Verbindungen ist eines der fundamentalsten
Probleme der modernen organischen Chemie. Effektive Lösungen müssen die spezifische …

We report herein the development of a general and mild protocol of oxygen-promoted Pd (II)
catalysis resulting in the selective cross-couplings of alkenyl-and arylboron compounds with …

Recently, dispersions of gold nanoclusters in liquid media (colloidal nanogold) have been
extensively used as quasi‐homogeneous catalysts for various aerobic oxidation reactions …