Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

A highly selective and general photoinduced C–Cl borylation protocol that employs [Ni
(IMes) 2](IMes= 1, 3-dimesitylimidazoline-2-ylidene) for the radical borylation of …

A series of studies have been conducted by experimental and theoretical methods on the
synthesis, structures, and reactions of Cp* Rh boryl complexes that are likely intermediates …

Over the past decade, transition metal complexes of boron have become established as the
fourth class of compounds involving direct metal–boron interactions. In contrast to the other …

The metal-catalyzed borylation of alkenes, alkynes, and organic electrophiles with B B
compounds was developed for the synthesis of organoboronic esters from simple organic …

The reactions of the B B-bonded compounds B2 (cat) 2 (cat= 1, 2-O2C6H4)(1a), B2 (4-
Butcat) 2 (1b), and B2 (OCMe2CMe2O) 2 (1c) with the Pt (0)-bis (phosphine) complex …

Rapid advances have been made over the past few years in the chemistry of transition metal
complexes with σ‐bonded boryl and borylene ligands. The use of suitable substituents on …

In this feature article, we discuss selected recent aspects of metal boryl (M–BR2) chemistry
pertaining, in particular, to the role of late and post-transition metal boryl complexes in …