Magic‐Sized Stoichiometric II–VI Nanoclusters

MS Bootharaju, W Baek, S Lee, H Chang, J Kim… - Small, 2021 - Wiley Online Library
Metal chalcogenide nanomaterials have gained widespread interest in the past two decades
for their potential optoelectronic, energy, and catalytic applications. The colloidal growth of …

Generalized and facile synthesis of semiconducting metal sulfide nanocrystals

J Joo, HB Na, T Yu, JH Yu, YW Kim, F Wu… - Journal of the …, 2003 - ACS Publications
We report on the synthesis of semiconductor nanocrystals of PbS, ZnS, CdS, and MnS
through a facile and inexpensive synthetic process. Metal− oleylamine complexes, which …

Tandem silver cluster isomerism and mixed linkers to modulate the photoluminescence of cluster‐assembled materials

RW Huang, XY Dong, BJ Yan, XS Du… - Angewandte Chemie …, 2018 - Wiley Online Library
Silver chalcogenolate cluster assembled materials (SCAMs) are a category of promising
light‐emitting materials the luminescence of which can be modulated by variation of their …

Highly luminescent and catalytically active suprastructures of magic-sized semiconductor nanoclusters

W Baek, MS Bootharaju, KM Walsh, S Lee… - Nature Materials, 2021 - nature.com
Metal chalcogenide magic-sized nanoclusters have shown intriguing photophysical and
chemical properties, yet ambient instability has hampered their extensive applications. Here …

Applications of metal selenium/tellurium compounds in materials science

VK Jain, G Kedarnath - Physical Sciences Reviews, 2019 - degruyter.com
Metal chalcogenides are technologically important materials. Physical, chemical, electrical
and mechanical properties of these materials can be fine-tuned by manipulating their shape …

Controlled Synthesis of Ternary II− II '− VI Nanoclusters and the Effects of Metal Ion Distribution on Their Spectral Properties

MW DeGroot, NJ Taylor, JF Corrigan - Inorganic chemistry, 2005 - ACS Publications
The reaction of [(3, 5-Me2-C5H3N) 2Zn (ESiMe3) 2](E= Se, Te) with cadmium (II) acetate in
the presence of PhESiMe3 and P n Pr3 at low temperature leads to the formation of single …

Heterometallic chalcogenido clusters containing lanthanides and main group metals: Emissive precursors to ternary solid-state compounds

A Kornienko, S Banerjee, GA Kumar… - Journal of the …, 2005 - ACS Publications
Heterometallic clusters containing lanthanides and the group 12 metals can be isolated as
crystalline compounds in high yields. These products [(py) 8Ln4M2Se6 (SePh) 4 (Ln= Er …

Ortho‐Chalcogenotetrelate Anions as Chelating Ligands: Syntheses and Characterization of [K6 (MeOH) 9][Sn2Se6][Cr (en) 2 (SnSe4)] 2,[Na (H2O) 4][Cr (en) 3] 2 …

M Melullis, MK Brandmayer… - … für anorganische und …, 2006 - Wiley Online Library
Abstract Reactions of K4 SnSe4, Na4 GeS4 or Ba2 GeSe4 with different 1, 2‐diaminoethane
(= en) coordinated complexes of CrCl3 (Cr (en) 2Cl2 Cl or Cr (en) 3 Cl3) in MeOH or …

Simple but effective: thermally stable Cu–ESiMe 3 via NHC ligation

MA Fard, F Weigend, JF Corrigan - Chemical Communications, 2015 - pubs.rsc.org
A series of thermally stable N-heterocyclic copper–chalcogenolate complexes of the general
formula [(IPr) Cu–ESiMe3](IPr= 1, 3-bis (2, 6-diisopropylphenyl) imidazolin-2-ylidene; E= S …

Stable ‐ESiMe3 Complexes of CuI and AgI (E=S, Se) with NHCs: Synthons in Ternary Nanocluster Assembly

M Azizpoor Fard, TI Levchenko… - … A European Journal, 2016 - Wiley Online Library
As a part of efforts to prepare new “metallachalcogenolate” precursors and develop their
chemistry for the formation of ternary mixed‐metal chalcogenide nanoclusters, two sets of …