Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

Heterocyclic compounds are the fundamental structural motifs distributed in natural
products, pharmaceuticals and biologically active compounds. Thus, there is increasing …

Chiral cyclopentadienyl rhodium (CpRh) complex‐catalyzed asymmetric C− H
functionalization reactions have witnessed a significant progress in organic synthesis. In …

Asymmetric ring-opening of 7-oxabenzonorbornadienes is achieved via Co-catalyzed indole
C–H functionalization. The utilization of chiral Co-catalyst consisting of a binaphthyl-derived …

The amide is one of the most prevalent functional groups in all of pharmaceuticals, and for
this reason, reactions that introduce the amide moiety are of particular value. Intermolecular …

A series of rhodium complexes bearing sterically and electronically tunable
cyclopentadienyl ligands, prepared by utilizing Co2 (CO) 8-mediated [2+ 2+ 1] cyclization as …

An alcohol-directed, nickel-catalyzed three-component umpolung carboamination of
unactivated alkenes with aryl/alkenylboronic esters and electrophilic aminating reagents is …

In this report, distally disposed axial and central chirality has been installed in a synergistic
fashion via rhodium-catalyzed C–H alkylation of benzamides using N-arylmaleimide as the …

Catalytic carboamination of alkenes is a powerful synthetic tool to access valuable amine
scaffolds from abundant and readily available alkenes. Although a number of synthetic …

Heterocyclic compounds are widely present in the core structures of several natural
products, pharmaceuticals and agrochemicals, and thus great efforts have been devoted to …