Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …
occupy an important position. Unfortunately, no two nanoparticles from conventional …
Surface and interface control in nanoparticle catalysis
The surface and interfaces of heterogeneous catalysts are essential to their performance as
they are often considered to be active sites for catalytic reactions. With the development of …
they are often considered to be active sites for catalytic reactions. With the development of …
The critical impacts of ligands on heterogeneous nanocatalysis: A review
Ligand utilization is a necessary and powerful technique for the colloidal synthesis of
nanoparticles (NPs) with controllable sizes and regulated morphologies. For catalysis …
nanoparticles (NPs) with controllable sizes and regulated morphologies. For catalysis …
Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties
Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …
A Heteroleptic Gold Hydride Nanocluster for Efficient and Selective Electrocatalytic Reduction of CO2 to CO
It has been a long-standing challenge to create and identify the active sites of
heterogeneous catalysts, because it is difficult to precisely control the interfacial chemistry at …
heterogeneous catalysts, because it is difficult to precisely control the interfacial chemistry at …
Mediating CO2 Electroreduction Activity and Selectivity over Atomically Precise Copper Clusters
LJ Liu, ZY Wang, ZY Wang, R Wang… - Angewandte …, 2022 - Wiley Online Library
Atomically precise copper clusters are highly desirable catalysts for electrocatalytic CO2
reduction reaction (CO2RR) and provide an ideal platform for elaborating structure–activity …
reduction reaction (CO2RR) and provide an ideal platform for elaborating structure–activity …
Ligand design in ligand‐protected gold nanoclusters
The design of surface ligands is crucial for ligand‐protected gold nanoclusters (Au NCs).
Besides providing good protection for Au NCs, the surface ligands also play the following …
Besides providing good protection for Au NCs, the surface ligands also play the following …
From Single Crystal to Single Atom Catalysts: Structural Factors Influencing the Performance of Metal Catalysts for CO2 Electroreduction
With the electrochemical CO2 reduction reaction (CO2RR), CO2 can be used as a feedstock
to produce value-added chemicals and fuels while storing renewable energy. For its …
to produce value-added chemicals and fuels while storing renewable energy. For its …
Operando characterization techniques for electrocatalysis
The energy crisis and climate change are growing threats to human society. Fuel cells and
electrolyzers using solar and wind as energy sources provide a promising carbon-free and …
electrolyzers using solar and wind as energy sources provide a promising carbon-free and …
Body-Centered-Cubic-Kernelled Ag15Cu6 Nanocluster with Alkynyl Protection: Synthesis, Total Structure, and CO2 Electroreduction
G Deng, J Kim, MS Bootharaju, F Sun… - Journal of the …, 2022 - ACS Publications
While atomically monodisperse nanostructured materials are highly desirable to unravel the
size-and structure-catalysis relationships, their controlled synthesis and the atomic-level …
size-and structure-catalysis relationships, their controlled synthesis and the atomic-level …