Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R Jin, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Surface and interface control in nanoparticle catalysis

C Xie, Z Niu, D Kim, M Li, P Yang - Chemical reviews, 2019 - ACS Publications
The surface and interfaces of heterogeneous catalysts are essential to their performance as
they are often considered to be active sites for catalytic reactions. With the development of …

The critical impacts of ligands on heterogeneous nanocatalysis: A review

L Lu, S Zou, B Fang - ACS Catalysis, 2021 - ACS Publications
Ligand utilization is a necessary and powerful technique for the colloidal synthesis of
nanoparticles (NPs) with controllable sizes and regulated morphologies. For catalysis …

Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

A Heteroleptic Gold Hydride Nanocluster for Efficient and Selective Electrocatalytic Reduction of CO2 to CO

ZH Gao, K Wei, T Wu, J Dong, D Jiang… - Journal of the …, 2022 - ACS Publications
It has been a long-standing challenge to create and identify the active sites of
heterogeneous catalysts, because it is difficult to precisely control the interfacial chemistry at …

Mediating CO2 Electroreduction Activity and Selectivity over Atomically Precise Copper Clusters

LJ Liu, ZY Wang, ZY Wang, R Wang… - Angewandte …, 2022 - Wiley Online Library
Atomically precise copper clusters are highly desirable catalysts for electrocatalytic CO2
reduction reaction (CO2RR) and provide an ideal platform for elaborating structure–activity …

Ligand design in ligand‐protected gold nanoclusters

B Zhang, J Chen, Y Cao, OJH Chai, J Xie - Small, 2021 - Wiley Online Library
The design of surface ligands is crucial for ligand‐protected gold nanoclusters (Au NCs).
Besides providing good protection for Au NCs, the surface ligands also play the following …

From Single Crystal to Single Atom Catalysts: Structural Factors Influencing the Performance of Metal Catalysts for CO2 Electroreduction

CD Koolen, W Luo, A Züttel - ACS Catalysis, 2022 - ACS Publications
With the electrochemical CO2 reduction reaction (CO2RR), CO2 can be used as a feedstock
to produce value-added chemicals and fuels while storing renewable energy. For its …

Operando characterization techniques for electrocatalysis

J Li, J Gong - Energy & Environmental Science, 2020 - pubs.rsc.org
The energy crisis and climate change are growing threats to human society. Fuel cells and
electrolyzers using solar and wind as energy sources provide a promising carbon-free and …

Body-Centered-Cubic-Kernelled Ag15Cu6 Nanocluster with Alkynyl Protection: Synthesis, Total Structure, and CO2 Electroreduction

G Deng, J Kim, MS Bootharaju, F Sun… - Journal of the …, 2022 - ACS Publications
While atomically monodisperse nanostructured materials are highly desirable to unravel the
size-and structure-catalysis relationships, their controlled synthesis and the atomic-level …