Eighteen years ago in Angewandte Chemie John K. Stille reviewed a novel methodology,
which eventually became known by his name, for the coupling of organostannanes with …

The title of this article may sound paradoxical, since the first idea about fluorine in
coordination chemistry is that of being a common constituent of large and very weakly …

The so far accepted mechanism of the Stille reaction (palladium-catalyzed cross-coupling of
organotin reagents with organic electrophiles) is criticized. Based on kinetic studies on …

The chemistry of binuclear palladium (II) and platinum (II) complexes has been reviewed.
This review deals with complexes derived from various classes of ligands and covers …

Abstract Vor achtzehn Jahren hat John K. Stille in der Angewandten Chemie über eine
neuartige Kupplung von Organostannanen mit organischen Elektrophilen berichtet, die …

The organoplatinum (II) complexes [(NN) PtMe2] and [(NN) PtPh2](NN= ArNC (Me) C (Me)
NAr, Ar= 2, 6-dichlorophenyl) can act as donor ligands for copper (I) and silver (I) triflates …

The relative rates of C− H activation of methane, methanol, and dimethyl ether by [(NN) PtMe
(TFE-d 3)]+((NN)= ArN C (Me)− C (Me) NAr; Ar= 3, 5-di-tert-butylphenyl, TFE-d 3 …

The applications of 19F NMR in the study of a number of problems in organometallic
chemistry are illustrated with relevant cases, paying special attention to the case of …

Abstract Arylallylpalladium complexes [Pd (5‐C6F5‐η3‐cyclohexenyl)(C6Cl2F3)(NCMe)](10
) and [Pd2 (μ‐C6Cl2F3) 2 (5‐C6F5‐1, 3‐η3‐cyclohexenyl) 2](13) have been synthesized …

The complexes [Pd (3, 5-C6Cl2F3) 2L2] and [Pd (C6F5) 2L2](L= SC4H8 (tht), or SMe2) react
in CCl3D to give a mixture also containing the heteroaryl products [Pd (3, 5-C6Cl2F3)(C6F5) …