Why does industry not use immobilized transition metal complexes as catalysts?

S Hübner, JG de Vries, V Farina - Advanced Synthesis & …, 2016 - Wiley Online Library
Much effort has gone into the immobilization of homogeneous catalysts based on the idea
that in this way the catalysts could be not only separated more easily from the product but …

Heterogeneous catalysis in continuous flow microreactors: A review of methods and applications

A Tanimu, S Jaenicke, K Alhooshani - Chemical Engineering Journal, 2017 - Elsevier
Over the past two decades, microreactor technology has evolved to become a crucial
component in the development of process intensification. Microreactors have helped to …

Carbon− carbon coupling reactions catalyzed by heterogeneous palladium catalysts

L Yin, J Liebscher - Chemical Reviews, 2007 - ACS Publications
Homogeneous palladium catalysis has gained enormous relevance in various coupling
reactions such as Heck, Stille, Suzuki, Sonogashira, and Buchwald-Hartwig reactions. Many …

On the nature of the active species in palladium catalyzed Mizoroki–Heck and Suzuki–Miyaura couplings–homogeneous or heterogeneous catalysis, a critical review

NTS Phan, M Van Der Sluys… - Advanced Synthesis & …, 2006 - Wiley Online Library
A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki
coupling reactions over the last 15 years. Historically, nearly every form of palladium used …

The potential of palladacycles: more than just precatalysts

J Dupont, CS Consorti, J Spencer - Chemical Reviews, 2005 - ACS Publications
The past half century has witnessed enormous growth in transition-metal organometallic
chemistry, both as a scientific discipline and as a subject for research and applications in …

Ordered mesoporous and microporous molecular sieves functionalized with transition metal complexes as catalysts for selective organic transformations

DE De Vos, M Dams, BF Sels, PA Jacobs - Chemical Reviews, 2002 - ACS Publications
Immobilization of catalysts on inorganic matrices has several important potential advantages
over other approaches such as the use of organic polymer supports. The chemical stability …

Silica-supported palladium: Sustainable catalysts for cross-coupling reactions

V Polshettiwar, C Len, A Fihri - Coordination Chemistry Reviews, 2009 - Elsevier
Heterogeneous palladium (Pd) catalyst systems are among the most widely used for the
formation of carbon–carbon and carbon–nitrogen bonds. The majority of the novel …

Palladium catalysts for the Suzuki cross-coupling reaction: an overview of recent advances

F Bellina, A Carpita, R Rossi - Synthesis, 2004 - thieme-connect.com
This review with 206 references covers the literature published until March 2004 on the
development and applications of new efficient catalyst systems for the Suzuki palladium …

High‐turnover palladium catalysts in cross‐coupling and Heck chemistry: A critical overview

V Farina - Advanced Synthesis & Catalysis, 2004 - Wiley Online Library
This review discusses the problems associated with developing high‐turnover catalysts for
the cross‐coupling and Heck reactions. New developments in the area, principally …

Non-conventional methodologies for transition-metal catalysed carbon–carbon coupling: A critical overview. Part 2: The Suzuki reaction

F Alonso, IP Beletskaya, M Yus - Tetrahedron, 2008 - Elsevier
In a previous and recent report, 1 we have highlighted in the introductory section the
transition-metal catalysed carbone carbon bond formation as a fundamental reaction in …