Super atomic clusters: design rules and potential for building blocks of materials
P Jena, Q Sun - Chemical reviews, 2018 - ACS Publications
Atomic clusters, consisting of a few to a few thousand atoms, have emerged over the past 40
years as the ultimate nanoparticles, whose structure and properties can be controlled one …
years as the ultimate nanoparticles, whose structure and properties can be controlled one …
Gas-phase ion chemistry of [B12X12] 2−(X= F, Cl, Br, I, CN) A brief review of twelve years of researching twelve− vertexed dianions and their fragments
J Warneke - International Journal of Mass Spectrometry, 2023 - Elsevier
The closo-dodecaborate dianions [B 12 X 12] 2−(X= halogen, CN) have been recognized in
recent years for their outstanding physical and chemical properties. Gas-phase ion …
recent years for their outstanding physical and chemical properties. Gas-phase ion …
Design and performance of a soft-landing instrument for fragment ion deposition
HY Samayoa-Oviedo, KA Behrend, S Kawa… - Analytical …, 2021 - ACS Publications
We report the development of a new high-flux electrospray ionization-based instrument for
soft landing of mass-selected fragment ions onto surfaces. Collision-induced dissociation is …
soft landing of mass-selected fragment ions onto surfaces. Collision-induced dissociation is …
Rational design of an argon-binding superelectrophilic anion
M Mayer, V Van Lessen… - Proceedings of the …, 2019 - National Acad Sciences
Chemically binding to argon (Ar) at room temperature has remained the privilege of the most
reactive electrophiles, all of which are cationic (or even dicationic) in nature. Herein, we …
reactive electrophiles, all of which are cationic (or even dicationic) in nature. Herein, we …
Catalytic Potential of [B12X11]2– (X = F, Cl, Br, I, CN) Dianions
Dodecaborate anions ([B12H12] 2–) and their derivatives where hydrogen atoms are
replaced by halogen, pseudohalogen, or superhalogen moieties belong to a class of very …
replaced by halogen, pseudohalogen, or superhalogen moieties belong to a class of very …
Stability of B12(CN)122−: Implications for Lithium and Magnesium Ion Batteries
Multiply charged negative ions are seldom stable in the gas phase. Electrostatic repulsion
leads either to autodetachment of electrons or fragmentation of the parent ion. With a …
leads either to autodetachment of electrons or fragmentation of the parent ion. With a …
Electronic Structure and Stability of [B12X12]2– (X = F–At): A Combined Photoelectron Spectroscopic and Theoretical Study
The stability and electron loss process of numerous multiply charged anions (MCAs) have
been traditionally explained in terms of the classical Coulomb interaction between spatially …
been traditionally explained in terms of the classical Coulomb interaction between spatially …
Superelectrophilic Behavior of an Anion Demonstrated by the Spontaneous Binding of Noble Gases to [B12Cl11]−
M Rohdenburg, M Mayer, M Grellmann… - Angewandte Chemie …, 2017 - Wiley Online Library
It is common and chemically intuitive to assign cations electrophilic and anions nucleophilic
reactivity, respectively. Herein, we demonstrate a striking violation of this concept: The anion …
reactivity, respectively. Herein, we demonstrate a striking violation of this concept: The anion …
On the Oxidation of the Three‐Dimensional Aromatics [B12X12]2− (X=F, Cl, Br, I)
RT Boeré, J Derendorf, C Jenne… - … A European Journal, 2014 - Wiley Online Library
The perhalogenated closo‐dodecaborate dianions [B12X12] 2−(X= H, F, Cl, Br, I) are three‐
dimensional counterparts to the two‐dimensional aromatics C6X6 (X= H, F, Cl, Br, I) …
dimensional counterparts to the two‐dimensional aromatics C6X6 (X= H, F, Cl, Br, I) …
Direct functionalization of C− H bonds by electrophilic anions
J Warneke, M Mayer, M Rohdenburg… - Proceedings of the …, 2020 - National Acad Sciences
Alkanes and [B12X12] 2−(X= Cl, Br) are both stable compounds which are difficult to
functionalize. Here we demonstrate the formation of a boron− carbon bond between these …
functionalize. Here we demonstrate the formation of a boron− carbon bond between these …