The discovery of decamethyldizincocene [Zn2 (η5-Cp*) 2](Cp*= C5Me5), the first complex
containing a covalent zinc–zinc bond, by Carmona in 2004 initiated the search for this …

Atom‐precise, ligand‐stabilized metalloid clusters have emerged as outstanding model
systems to study fundamental structure and bonding situations of compositionally related …

Abstract The triangular clusters [Zn3Cp* 3]+ and [Zn2CuCp* 3] were obtained by addition of
the in situ generated, electrophilic, and isolobal species [ZnCp*]+ and [CuCp*] to Carmona's …

A series of zero-valent palladium complexes featuring diphosphinometal ligands is reported.
The metalloligand in the PMP-type framework (M= LiI, CuI, ZnII) acts as a weak to medium …

In this manuscript we report the preparation of four new zinc complexes,[{(μ-CH3COO)
ZnL1} 2Zn]· 2DMSO (1),[{(DMF) ZnL1 (μ-CH3COO) ZnL1Zn (N3)}]· 0.64 DMSO· 0.36 EtOH …

Electrophilic fluorinating reagents derived from fluoride are desirable for the synthesis of 18F-
labeled molecules for positron emission tomography (PET). Here, we study the mechanism …

Heteronuclear metal complexes comprising main group metals and transition metals have
attracted widespread attention from researchers due to their applications in stoichiometric …

Pd‐mediated Negishi cross‐coupling reactions were studied by a combination of kinetic
measurements, electrospray‐ionization (ESI) mass spectrometry, 31P NMR and UV/Vis …

Synthetic strategies and mechanistic pathways for the formation of transition metal–
organozinc compounds and their structural properties are reviewed. Herein, two groups of …

Recent advances on low valent main group metal chemistry have shown the excellent
potential of heterobimetallic complexes derived from Al (I) to promote cooperative small …