The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …

Photoredox catalysis of organic reactions driven by iron has attracted substantial attention
throughout recent years, due to potential environmental and economic benefits. In this …

Catalytic C (sp3)–H functionalization has provided enormous opportunities to construct
organic molecules, facilitating the derivatization of complex pharmaceutical compounds …

Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

Borylations of inert carbon–hydrogen bonds are highly useful for transforming feedstock
chemicals into versatile organoboron reagents. Catalysis of these reactions has historically …

The intermediacy of alkoxy radicals in cerium-catalyzed C–H functionalization via H-atom
abstraction has been unambiguously confirmed. Catalytically relevant Ce (IV)–alkoxide …

Organoboron compounds are of high significance in organic synthesis due to the unique
versatility of boryl substituents to access further modifications. The high demand for the …

Polystyrene upcycling to valuable commodity feedstocks is essential for reducing plastic
waste. Photooxidative degradation has emerged as a method for converting polystyrene to …

The selective functionalization of alkanes has long been recognized as a prominent
challenge and an arduous task in organic synthesis. Hydrogen atom transfer (HAT) …

Chiral α-aryl N-heterocycles are commonly found in natural products, pharmaceutical
agents, and chiral catalysts but remain challenging to access via asymmetric catalysis …