Activation of dinitrogen by polynuclear metal complexes
Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes
by which this fixation occurs have been a longstanding and significant research focus within …
by which this fixation occurs have been a longstanding and significant research focus within …
Nickel hydride complexes
NA Eberhardt, H Guan - Chemical reviews, 2016 - ACS Publications
Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
Nickel‐Catalyzed Asymmetric Synthesis of α‐Arylbenzamides
S Cuesta‐Galisteo, J Schörgenhumer… - Angewandte …, 2021 - Wiley Online Library
A nickel‐catalyzed asymmetric reductive hydroarylation of vinyl amides to produce
enantioenriched α‐arylbenzamides is reported. The use of a chiral bisimidazoline (BIm) …
enantioenriched α‐arylbenzamides is reported. The use of a chiral bisimidazoline (BIm) …
Complexes of Ni (I): a “rare” oxidation state of growing importance
Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as
well as in chemical applications such as the catalytic transformation of organic substrates …
well as in chemical applications such as the catalytic transformation of organic substrates …
Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis
We report the synthesis and characterization of a series of nickel complexes of the chelating
diphosphine-borane ligands ArB (o-Ph2PC6H4) 2 ([ArDPBPh]; Ar= Ph, Mes). The [ArDPBPh] …
diphosphine-borane ligands ArB (o-Ph2PC6H4) 2 ([ArDPBPh]; Ar= Ph, Mes). The [ArDPBPh] …
Boryl–metal bonds facilitate cobalt/nickel-catalyzed olefin hydrogenation
New approaches toward the generation of late first-row metal catalysts that efficiently
facilitate two-electron reductive transformations (eg, hydrogenation) more typical of noble …
facilitate two-electron reductive transformations (eg, hydrogenation) more typical of noble …
The chemistry of univalent metal β-diketiminates
YC Tsai - Coordination Chemistry Reviews, 2012 - Elsevier
The easily electronically and sterically tunable β-diketiminates are widely used auxiliary
ligands for the creation of a wide range of metal complexes with various oxidation states in …
ligands for the creation of a wide range of metal complexes with various oxidation states in …
A d10 Ni–(H2) Adduct as an Intermediate in HH Oxidative Addition across a NiB Bond
Abstract Bifunctional E H activation offers a promising approach for the design of two‐
electron‐reduction catalysts with late first‐row metals, such as Ni. To this end, we have been …
electron‐reduction catalysts with late first‐row metals, such as Ni. To this end, we have been …
Activation of small molecules at nickel (I) moieties
P Zimmermann, C Limberg - Journal of the American Chemical …, 2017 - ACS Publications
The activation and selective transformation of virtually inexhaustible or easy-to-generate
chemicals like N2, O2, CO2, CO, H2, or methane gas to value-added products is a lively …
chemicals like N2, O2, CO2, CO, H2, or methane gas to value-added products is a lively …
Lessons from isolable nickel (I) precursor complexes for small molecule activation
Small-molecule activation by transition metals is essential to numerous organic
transformations, both biological and industrial. Creating useful metal-mediated activation …
transformations, both biological and industrial. Creating useful metal-mediated activation …