Palladium-Catalyzed Carbonylations: Application in Complex Natural Product Total Synthesis and Recent Developments

HS Sims, M Dai - The Journal of Organic Chemistry, 2023 - ACS Publications
Carbon monoxide is a cheap and abundant C1 building block that can be readily
incorporated into organic molecules to rapidly build structural complexity. In this Perspective …

Recent Advances in Base‐Metal‐Catalyzed Carbonylation of Unactivated Alkyl Electrophiles

W Li, D Jiang, C Wang, LJ Cheng - Chinese Journal of …, 2023 - Wiley Online Library
Comprehensive Summary Transition metal‐catalyzed carbonylation reactions represent a
direct and atom‐economical approach to synthesize carbonyl compounds or their …

Electrochemical Sulfonylation/Cyclization of N-Alkenylacrylamides with Sodium Sulfinates or Sulfonyl Hydrazides

ZX Yang, LC Ding, GH Yang, D Wang… - The Journal of …, 2024 - ACS Publications
Two general protocols for the regioselective electrochemically enabled sulfonylation
cyclization of N-alkenylacrylamides with sodium sulfinates or sulfonyl hydrazides were …

A monolayer crystalline covalent network of polyoxometalate clusters

H Li, L Zheng, Q Lu, Z Li, X Wang - Science Advances, 2023 - science.org
Monolayer two-dimensional (2D) materials are of great interest because of their unique
electronic structures, noticeable in-plane confinement effect, and exceptional catalytic …

Manganese-Catalyzed Carbonylation of Unactivated Alkyl Bromides with Alkylidenecyclopropanes

PR Liu, MM Ji, JB Hu, JB Peng - ACS Catalysis, 2024 - ACS Publications
The transition-metal-catalyzed carbonylation reaction has emerged as a powerful method for
the construction of carbonyl compounds. However, very few examples have worked for the …

Manganese-Catalyzed Alkoxycarbonylation of Alkyl Chlorides

HJ Ai, HQ Geng, XW Gu, XF Wu - ACS Catalysis, 2023 - ACS Publications
The carbonylative transformation of alkyl chlorides, a class of cheap chemical feedstock, is
among the most challenging tasks in the field of carbonylation due to the difficulty of C (sp3) …

Ligand-Free Iron-Catalyzed Carbonylation of Aryl Iodides with Alkenyl Boronic Acids: Access to α, β-Unsaturated Ketones

N Xu, J Chen, K Sun, W Han - Organic Letters, 2024 - ACS Publications
The application of earth-abundant and low-toxicity iron catalysts as replacements for
palladium in carbonylative coupling reactions remains challenging and largely unexplored …

SET or TET? Iron-catalyzed aminocarbonylation of unactivated alkyl halides with amines, amides, and indoles via a substrate dependent mechanism

HJ Ai, F Zhao, XF Wu - Chinese Journal of Catalysis, 2023 - Elsevier
Iron-catalyzed carbonylation reactions are highly desirable in our sustainability-advocating
chemical community because of its low cost, abundance, and potential for distinct and …

Recent Advances in Non-Precious Metal Catalysis

E Chong, H Wu, J Lee, K Forson… - … Process Research & …, 2023 - ACS Publications
This Review offers a comprehensive overview of the latest advancements in nonprecious
metal catalysis (NPMC) research, focusing on the period between July and October 2022 …

Abundant metal-catalyzed carbonylation of alkyl bromides and alkyl chlorides

XW Gu, XF Wu - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
Transition metal-catalyzed carbonylation of alkyl halides is one of the most efficient methods
for the assembly of aliphatic carbonyl-containing compounds. Despite the long history of …