Chemical reactivity of lithium doped monolayer and bilayer graphene

PA Denis - The Journal of Physical Chemistry C, 2011 - ACS Publications
Herein, we perform a comparative investigation on the reactivity of pristine and lithium
doped monolayer and bilayer graphene. To study the addition of free radicals and 1, 3 …

In Situ Measurement of CO2 and H2O Adsorption by ZIF-8 Films

F Tian, AM Mosier, A Park, ER Webster… - The Journal of …, 2015 - ACS Publications
The adsorption of CO2 and H2O by ZIF-8 thin films was investigated using X-ray
photoelectron spectroscopy (XPS) and temperature-programmed desorption (TPD) in situ …

Direct oxidation of methane to methanol on single-site copper-oxo species of copper porphyrin functionalized graphene: A DFT study

T Quinn, P Choudhury - Molecular Catalysis, 2017 - Elsevier
In this work, we discuss the study of large macro-cyclic molecules, copper porphyrins (CuP),
as the single-site active metal center for the methane catalytic oxidation. This work shows …

Reaction of the basal plane of graphite with the methyl radical

L Mandeltort, P Choudhury, JK Johnson… - The Journal of …, 2012 - ACS Publications
The reaction of methyl radicals with the basal plane of graphite has been observed to occur
with an activation energy of less than 0.3 eV. This reaction is initiated by Li-induced CH3Cl …

Methyl radical reactivity on the basal plane of graphite

L Mandeltort, P Choudhury, JK Johnson… - The Journal of …, 2012 - ACS Publications
The reaction of submonolayer Li atoms with CH3Cl at 100 K on a highly oriented pyrolytic
graphite (HOPG) surface has been studied under ultrahigh vacuum. We exploit the low …

Electronic Descriptor of Single Metal-Oxo Species on Phthalocyanine-and Porphyrin-Functionalized Graphene toward Methane Activation Process

D Filonowich, M Luna, T Quinn… - The Journal of Physical …, 2020 - ACS Publications
Catalysts are needed to expedite methane-to-methanol conversion reactions by lowering
the energy required for the reactions to produce high-value-added chemicals. In this work …

Improving the chemical reactivity of single-wall carbon nanotubes with lithium doping

PA Denis - The Journal of Physical Chemistry C, 2011 - ACS Publications
The effect of lithium doping on the reactivity of single-wall carbon nanotubes (SWCNTs) was
studied by means of first principle calculations. Two prototype reactions were considered …

Theoretical study of the adsorption of substituted guaiacol and catechol radicals on a graphite surface

LI Perea-Ramírez, R Vargas, Z Domínguez… - Electrochimica …, 2017 - Elsevier
Adsorption of radicals obtained from catechol and guaiacol derivatives, on a graphite
surface, was theoretically analyzed in the context of electrografting process. It was …

Methyl Chloride Reactions on Lithiated Carbon Nanotubes: Lithium as Both Reactant and Catalyst

P Choudhury, JK Johnson - The Journal of Physical Chemistry C, 2011 - ACS Publications
Recent experimental work has shown that CH3Cl reacts with lithiated single-walled carbon
nanotubes (SWNTs) at low temperatures. The reaction was shown to be irreversible …

Adsorption/Desorption—Thermal

JT Yates Jr, JT Yates - Experimental Innovations in Surface Science: A …, 2015 - Springer
The study of the surface behavior of high area solids can be carried out using extensions of
the fundamental measurement methods developed for studies of low area single crystal …