Vinyl pnictinidenes are an elusive family of molecules that have been suggested as key
intermediates in multiple chemical reactions and commonly display a predisposition toward …

Carbonyl nitrenes are versatile intermediates that have been extensively characterized;
however, their phosphorus analogues remain largely unknown. Herein, we report the …

Carbenes and nitrenes are key intermediates involved in numerous chemical processes,
and they have attracted considerable attention in synthetic chemistry, biochemistry, and …

The simplest diphosphene HPPH and isomeric diphosphinyldene PPH2 features prototype
phosphorus‐phosphorus multiple bonding properties that have been of long‐standing …

The perfluorinated silylphosphinidene, F3SiP, in the triplet ground state is generated by the
reaction of laser-ablated silicon atoms with PF3 in solid neon and argon matrices. The …

The vibrational spectra of the simplest phosphaketene HPCO and its isotopologue DPCO in
solid Ar-matrices at 12.0 K have been analyzed with the aid of the computations at the …

Phosphinidenes are heavy congeners of nitrenes that have been broadly used as in situ
reagents in synthetic phosphorus chemistry and also serve as versatile ligands in …

Until now, there has been very little experimental evidence for the existence of free
arsinidenes and stibinidenes, apart from the hydrides, AsH and SbH. Here, we report on …

The highly labile complexes between phosphaethyne (HCP) and hydrogen chloride (HCl)
with 1: 1 and 1: 2 stoichiometries have been generated in Ar and N2 matrices at 10 K …

The HBP radical was generated via the reaction of laser ablated boron atom with PH3 in a
solid neon matrix, which is identified via IR spectroscopy with isotopic substitutions and …