Divergent gold catalysis: unlocking molecular diversity through catalyst control

CC Chintawar, AK Yadav, A Kumar… - Chemical …, 2021 - ACS Publications
The catalyst-directed divergent synthesis, commonly termed as “divergent catalysis”, has
emerged as a promising technique as it allows chartering of structurally distinct products …

Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis

L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Recent developments in enantioselective transition metal catalysis featuring attractive noncovalent interactions between ligand and substrate

A Fanourakis, PJ Docherty, P Chuentragool… - ACS …, 2020 - ACS Publications
Enantioselective transition metal catalysis is an area very much at the forefront of
contemporary synthetic research. The development of processes that enable the efficient …

Main avenues in gold coordination chemistry

RP Herrera, MC Gimeno - Chemical Reviews, 2021 - ACS Publications
In this contribution, we provide an overview of the main avenues that have emerged in gold
coordination chemistry during the last years. The unique properties of gold have motivated …

Synthetic routes to late transition metal–NHC complexes

T Scattolin, SP Nolan - Trends in Chemistry, 2020 - cell.com
Transition metal complexes bearing N-heterocyclic carbene ligands (NHCs) have gained a
place of crucial importance in numerous areas of research such as medicinal chemistry …

Homogeneous gold redox chemistry: organometallics, catalysis, and beyond

B Huang, M Hu, FD Toste - Trends in chemistry, 2020 - cell.com
Gold redox chemistry holds the promise of unique reactivities and selectivities that are
different to other transition metals. Recent studies have utilized strain release, ligand design …

Coordination versatility of NHC-metal topologies in asymmetric catalysis: Synthetic insights and recent trends

A Jayaraj, AV Raveedran, AT Latha… - Coordination Chemistry …, 2023 - Elsevier
Asymmetric metal based catalysis has advanced quickly in recent years, with its efficiency
relying exclusively on chiral ligands. Rational design and meticulous selection of chiral …

Recent advances in the development of chiral gold complexes for catalytic asymmetric catalysis

JJ Jiang, MK Wong - Chemistry–An Asian Journal, 2021 - Wiley Online Library
Asymmetric gold catalysis has been rapidly developed in the past ten years. Breakthroughs
have been made by rational design and meticulous selection of chiral ligands. This review …

Control of Selectivity in Homogeneous Catalysis through Noncovalent Interactions

KT Mahmudov, AJL Pombeiro - Chemistry–A European …, 2023 - Wiley Online Library
Abstract The regio‐, site‐, stereo‐or chemoselective homogeneous catalytic transformations
are extremely important for the growth/success of the current chemical industry. Based on …

Mechanistic Inference from Statistical Models at Different Data-Size Regimes

DM Lustosa, A Milo - ACS Catalysis, 2022 - ACS Publications
The chemical sciences are witnessing an influx of statistics into the catalysis literature.
These developments are propelled by modern technological advancements that are leading …