Conspectus Ynamides are electron-rich heteroatom-substituted alkynes with a C–C triple
bond directly attached to the amide group. Importantly, this amide group is able to impose an …

Alkynes represent one of the most important and versatile building blocks in organic
synthesis. Heteroatom-substituted alkynes, which can be considered as subgroups of …

Ynamides display an exceptionally fine balance between stability and reactivity. They also
offer unique and multiple opportunities for the inclusion of nitrogen‐based functionalities into …

In the past four decades, allenes have progressively risen from an unenviable status of
being a structural curiosity to becoming one of the most powerful and versatile synthetic …

A practical cross-coupling of amides with alkynyl bromides using catalytic CuSO4⊙ 5H2O
and 1, 10-phenanthroline is described here. This catalytic protocol is more environmentally …

The Emergence of Allenamides in Organic Synthesis | Accounts of Chemical Research ACS
ACS Publications C&EN CAS Find my institution Log In Accounts of Chemical Research ACS …

Alkynes are among the most important building blocks in organic synthesis. The richness of
this functional group renders it extremely versatile as a synthon for a diverse array of modern …

A copper-catalyzed new C− N bond formation involving a sp-hybridized carbon is described
here leading to a facile entry for syntheses of chiral ynamides. This direct N-alkynylation of …

A general and efficient method for the coupling of a wide range of amides with alkynyl
bromides is described here. This novel amidation reaction involves a catalytic protocol using …

The highly enantioselective synthesis of densely functionalized 2, 3-indoline-cyclobutanes
by means of chiral gold catalysis is presented. Intermolecular formal [2+ 2]-cycloaddition …