Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …
their ability to open and close their pores in an adaptive manner induced by chemical and …
Evaluation of the BET Theory for the Characterization of Meso and Microporous MOFs
Surface area determination with the Brunauer–Emmett–Teller (BET) method is a widely
used characterization technique for metal–organic frameworks (MOFs). Since these …
used characterization technique for metal–organic frameworks (MOFs). Since these …
Four-dimensional metal-organic frameworks
Recognising timescale as an adjustable dimension in porous solids provides a new
perspective to develop novel four-dimensional framework materials. The deliberate design …
perspective to develop novel four-dimensional framework materials. The deliberate design …
Tailoring the separation properties of flexible metal-organic frameworks using mechanical pressure
Metal-organic frameworks are widely considered for the separation of chemical mixtures due
to their adjustable physical and chemical properties. However, while much effort is currently …
to their adjustable physical and chemical properties. However, while much effort is currently …
Investigating the mechanical stability of flexible metal–organic frameworks
As we continue to develop metal–organic frameworks (MOFs) for potential industrial
applications, it becomes increasingly imperative to understand their mechanical stability …
applications, it becomes increasingly imperative to understand their mechanical stability …
Metal–organic frameworks under pressure
IE Collings, AL Goodwin - Journal of Applied Physics, 2019 - pubs.aip.org
Metal–organic frameworks (MOFs) are a broad and interesting class of materials known for
their mechanical flexibility. As such, their response to pressure is usually extreme and often …
their mechanical flexibility. As such, their response to pressure is usually extreme and often …
Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks
Switchable metal-organic frameworks (MOFs) have been proposed for various energy-
related storage and separation applications, but the mechanistic understanding of …
related storage and separation applications, but the mechanistic understanding of …
Structural Chemistry of Metal–Organic Frameworks under Hydrostatic Pressures
P Vervoorts, J Stebani, ASJ Mendez… - ACS Materials …, 2021 - ACS Publications
Studying the structural behavior of metal–organic frameworks (MOFs) under hydrostatic
pressures is a steadily growing area. The goal of active research is identification of …
pressures is a steadily growing area. The goal of active research is identification of …
Functionalization-induced breathing control in metal–organic frameworks for methane storage with high deliverable capacity
Metal–organic frameworks (MOFs) that can undergo structural flexibility upon gas sorption
cycle bear enormous potential particularly as adsorbents for methane storage. A molecular …
cycle bear enormous potential particularly as adsorbents for methane storage. A molecular …
Pore closure in zeolitic imidazolate frameworks under mechanical pressure
We investigate the pressure-dependent mechanical behaviour of the zeolitic imidazolate
framework ZIF-4 (M (im) 2; M2+= Co2+ or Zn2+, im−= imidazolate) with high pressure …
framework ZIF-4 (M (im) 2; M2+= Co2+ or Zn2+, im−= imidazolate) with high pressure …