Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system

I Senkovska, V Bon, L Abylgazina, M Mendt… - Angewandte …, 2023 - Wiley Online Library
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …

The chemistry and applications of flexible porous coordination polymers

N Behera, J Duan, W Jin, S Kitagawa - EnergyChem, 2021 - Elsevier
Since the late 1990s, much progress has been made in the field of the chemistry of flexible
porous coordination polymers (PCPs). Various PCP architectures have been recognized …

Advances of electroactive metal–organic frameworks

C Cong, H Ma - Small, 2023 - Wiley Online Library
The preparation of electroactive metal–organic frameworks (MOFs) for applications of
supercapacitors and batteries has received much attention and remarkable progress during …

Multi-dimensional metal-organic frameworks based on mixed linkers: Interplay between structural flexibility and functionality

S Bhattacharyya, TK Maji - Coordination Chemistry Reviews, 2022 - Elsevier
Metal-organic frameworks (MOFs) are regarded widely because of their intriguing structural
dynamism, which sets them apart from other porous materials. Such structural flexibility or …

Crystallizing atomic xenon in a flexible MOF to probe and understand its temperature-dependent breathing behavior and unusual gas adsorption phenomenon

H Wang, M Warren, J Jagiello, S Jensen… - Journal of the …, 2020 - ACS Publications
Flexible metal–organic frameworks (MOFs) hold great promise as smart materials for
specific applications such as gas separation. These materials undergo interesting structural …

The state of the field: from inception to commercialization of metal–organic frameworks

Z Chen, MC Wasson, RJ Drout, L Robison… - Faraday …, 2021 - pubs.rsc.org
As chemists and materials scientists, it is our duty to synthesize and utilize materials for a
multitude of applications that promote the development of society and the well-being of its …

Theoretical isotherm equation for adsorption-induced structural transition on flexible metal–organic frameworks

S Hiraide, Y Sakanaka, Y Iida… - Proceedings of the …, 2023 - National Acad Sciences
Flexible metal–organic frameworks (MOFs) exhibit an adsorption-induced structural
transition known as “gate opening” or “breathing,” resulting in an S-shaped adsorption …

Growth mechanisms and anisotropic softness–dependent conductivity of orientation-controllable metal–organic framework nanofilms

MS Yao, K Otake, T Koganezawa… - Proceedings of the …, 2023 - National Acad Sciences
Conductive metal–organic frameworks (c MOFs) manifest great potential in modern
electrical devices due to their porous nature and the ability to conduct charges in a regular …

1H-Pyrazole-4-carboxylic acid-based metal–organic frameworks: multifaceted materials

RK Gupta, P Kallem, GG Luo, P Cui, Z Wang… - Coordination Chemistry …, 2023 - Elsevier
Abstract Metal-organic frameworks (MOFs), consisting of metal ions or clusters coordinated
with organic ligands, are a class of crystalline materials that have garnered widespread …

Selective crystallization via vibrational strong coupling

K Hirai, H Ishikawa, T Chervy, JA Hutchison… - Chemical science, 2021 - pubs.rsc.org
The coupling of (photo) chemical processes to optical cavity vacuum fields is an emerging
method for modulating molecular and material properties. Recent reports have shown that …