Asymmetric hydrogenation catalyzed by first-row transition metal complexes
J Wen, F Wang, X Zhang - Chemical Society Reviews, 2021 - pubs.rsc.org
This review provides a comprehensive view of the application of first-row transition metals in
asymmetric hydrogenation and asymmetric transfer hydrogenation. The catalytic behavior of …
asymmetric hydrogenation and asymmetric transfer hydrogenation. The catalytic behavior of …
Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration
JV Obligacion, PJ Chirik - Nature Reviews Chemistry, 2018 - nature.com
The addition of X3Si–H or X2B–H (X= H, OR or R) across a C–C multiple bond is a well-
established method for incorporating silane or borane groups, respectively, into …
established method for incorporating silane or borane groups, respectively, into …
Ligand Redox Activity of Organonickel Radical Complexes Governed by the Geometry
Nickel-catalyzed cross-coupling reactions often employ bidentate π-acceptor N-ligands to
facilitate radical pathways. This report presents the synthesis and characterization of a …
facilitate radical pathways. This report presents the synthesis and characterization of a …
Nickel hydride complexes
NA Eberhardt, H Guan - Chemical reviews, 2016 - ACS Publications
Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
Complexes of Ni (I): a “rare” oxidation state of growing importance
Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as
well as in chemical applications such as the catalytic transformation of organic substrates …
well as in chemical applications such as the catalytic transformation of organic substrates …
Reactivity of (bi-Oxazoline) organonickel Complexes and Revision of a Catalytic Mechanism
Bi-Oxazoline (biOx) has emerged as an effective ligand framework for promoting nickel-
catalyzed cross-coupling, cross-electrophile coupling, and photoredox-nickel dual catalytic …
catalyzed cross-coupling, cross-electrophile coupling, and photoredox-nickel dual catalytic …
Alkene hydrosilylation using tertiary silanes with α-diimine nickel catalysts. redox-active ligands promote a distinct mechanistic pathway from platinum catalysts
Combination of the readily available α-diimine ligand,((Ar N C (Me)) 2 Ar= 2, 6-iPr2–
C6H3),(iPrDI) with air-stable nickel (II) bis (carboxylates) generated a highly active catalyst …
C6H3),(iPrDI) with air-stable nickel (II) bis (carboxylates) generated a highly active catalyst …
Generation and Stabilization of a Dinickel Catalyst in a Metal‐Organic Framework for Selective Hydrogenation Reactions
Although many monometallic active sites have been installed in metal–organic frameworks
(MOFs) for catalytic reactions, there are no effective strategies to generate bimetallic …
(MOFs) for catalytic reactions, there are no effective strategies to generate bimetallic …
Ni (I)–X complexes bearing a bulky α-diimine ligand: synthesis, structure, and superior catalytic performance in the hydrogen isotope exchange in pharmaceuticals
The synthesis and spectroscopic characterization of a family of Ni–X (X= Cl, Br, I, H)
complexes supported by the bulky α-diimine chelate N, N′-bis (1 R, 2 R, 3 R, 5 S)-(−) …
complexes supported by the bulky α-diimine chelate N, N′-bis (1 R, 2 R, 3 R, 5 S)-(−) …
Redox activity of pyridine-oxazoline ligands in the stabilization of low-valent organonickel radical complexes
Low-valent organonickel radical complexes are common intermediates in cross-coupling
reactions and metalloenzyme-mediated processes. The electronic structures of N-ligand …
reactions and metalloenzyme-mediated processes. The electronic structures of N-ligand …