Often used as a common solvent for chemical reations and utilized widely in industry as a
reagent, N, N‐dimethylformamide (DMF) has played an important role in organic synthesis …

Transition metal catalyzed carbonylation reactions using carbon monoxide as the C-1
source have occupied an all important position in catalysis which is subsequently related to …

Recently, carbonylation reactions have gained considerable interest as they are becoming a
versatile tool in the synthesis of pharmaceuticals, agrochemicals and their intermediates …

This account summarizes predominately our recent endeavors in developing CO gas-free
carbonylation reactions and the application of carbonylation reactions in the synthesis of …

The amide functionality is an important and pervasive structural motif in pharmacologically
active molecules, agrochemicals, peptides, and polymers. 1 Representative …

The Pd/C-catalyzed reactions, including reduction reactions and cross-coupling reactions,
play an irreplaceable role in modern organic synthesis. Compared to the homogeneous …

Carbonylation reaction is a very effective transformation for the synthesis of esters, amides,
and heterocyclic compounds. Heterogeneous catalyzed carbonylation reactions can be …

The rhodium (I)-catalyzed reaction of alkynes with 2-bromophenylboronic acids in the
presence of paraformaldehyde resulted in a CO gas-free carbonylative cyclization, yielding …

Immobilized palladium metal-containing ionic liquid (ImmPd-IL), a structurally well-defined
transition metal complex, is explored as an immobilized, phosphine-free catalyst for …

A simple method for the synthesis of amides has been developed by molybdenum-mediated
carbamoylation of aryl halides. Whereas the conventional palladium-catalyzed three …