Growing prospects of dynamic covalent chemistry in delivery applications
S Ulrich - Accounts of chemical research, 2019 - ACS Publications
Conspectus Delivery remains a major obstacle restricting the potential action of small
molecular drugs as well as novel biologics which cannot readily enter cells without the help …
molecular drugs as well as novel biologics which cannot readily enter cells without the help …
Dynamic covalent polymers for biomedical applications
The rapid development of supramolecular polymer chemistry and constitutional dynamic
chemistry over the last decades has made tremendous impact on the emergence of dynamic …
chemistry over the last decades has made tremendous impact on the emergence of dynamic …
Chitosan films as pH-responsive sustained release systems of naturally occurring antifungal volatile compounds
R Heras-Mozos, R Gavara, P Hernández-Muñoz - Carbohydrate polymers, 2022 - Elsevier
Reversible imine bonds have been used as a strategy to develop pH-dependent antifungal
systems based on grafting benzaldehyde and citral onto the surface of chitosan films …
systems based on grafting benzaldehyde and citral onto the surface of chitosan films …
Biopolymer@ metal-organic framework hybrid materials: a critical survey
Metal-organic frameworks (MOFs) are a class of pervasive nanostructured materials that
generate annually an incredible amount of work in different fields, spanning from separation …
generate annually an incredible amount of work in different fields, spanning from separation …
Supramolecular Polymers: Inherently Dynamic Materials
N Roy, V Schädler, JM Lehn - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus Since its inception in the early 1990s, the field of supramolecular polymers
(SPs) has grown into an interdisciplinary field of chemistry. It expanded from the self …
(SPs) has grown into an interdisciplinary field of chemistry. It expanded from the self …
Tunable interpenetrating polymer network hydrogels based on dynamic covalent bonds and metal–ligand bonds
H Yang, S Ghiassinejad, E Van Ruymbeke… - …, 2020 - ACS Publications
A series of tunable interpenetrating polymer network (IPN) hydrogels are designed by the
orthogonal incorporation of two distinct types of reversible bonds, ie, Schiff base bonds and …
orthogonal incorporation of two distinct types of reversible bonds, ie, Schiff base bonds and …
Remote-controlled exchange rates by photoswitchable internal catalysis of dynamic covalent bonds
DN Barsoum, VC Kirinda, B Kang… - Journal of the American …, 2022 - ACS Publications
The transesterification rate of boronate esters with diols is tunable over 14 orders of
magnitude. Rate acceleration is achieved by internal base catalysis, which lowers the …
magnitude. Rate acceleration is achieved by internal base catalysis, which lowers the …
Self‐Assembly in Water with N‐Substituted Imines
Imine synthesis has enjoyed a long history as the dynamic covalent reaction of choice for the
construction of purely covalent molecular architectures. In organic solvents, the formation of …
construction of purely covalent molecular architectures. In organic solvents, the formation of …
Using visible light to tune boronic acid–ester equilibria
JV Accardo, ER McClure, MA Mosquera… - Journal of the …, 2020 - ACS Publications
We report a series of azobenzene boronic acids that reversibly control the extent of diol
binding via photochemical isomerization. When the boronic acid is ortho to the azo group …
binding via photochemical isomerization. When the boronic acid is ortho to the azo group …
Enzymatic noncovalent synthesis of supramolecular soft matter for biomedical applications
Enzymatic noncovalent synthesis (ENS), a process that integrates enzymatic reactions and
supramolecular (ie, noncovalent) interactions for spatial organization of higher-order …
supramolecular (ie, noncovalent) interactions for spatial organization of higher-order …