The concept of aromaticity/antiaromaticity was recently extended to polynuclear transition
metal compounds. In the current report we review recent advances made in the field of …

Although aromaticity is a concept in chemistry, in the last years, special efforts have been
carried out in order to propose theoretical strategies to quantify it as a property of molecular …

Though aromaticity in compounds containing a transition-metal atom has already been
discussed for quite a long time, aromaticity in all-transition metal systems have been …

A model based on classical electrodynamics is used to measure the strength of ring currents
of different molecular orbitals, ie, σ‐and π‐orbitals, and characteristics of ring current loops …

Chemical bonding of neutral rhenium trichloride Re3Cl9 and doubly charged has been
brought into question in the current work. Despite recently reported propositions of π …

Metal clusters, an intermediate state between molecules and the extended solid, show
peculiar bonding and reactivity patterns. Their significance is critical to many areas …

The inclusion of relativistic effects always brings to the scientific community great and
stimulating surprises. To consider the spin–orbit term, which accounts for the interaction …

Relativistic effects are usually taken into account in heavy-element-containing species,
bringing to the scientific community stimulating cases of study. Scalar and spin–orbit effects …

We have theoretically evaluated the behavior of the Re3 (μ-Cl) 3Cl6 cluster under magnetic
perturbation, and it clearly shows that the magnetic response within the Re3 (μ-Cl) 3 plane is …

Molecular clusters can function as nanoscale atoms/superatoms, assembling into
superatomic solids, a new class of solid‐state materials with designable properties through …