Chemistry of the highly stable hindered cobalt sandwich compound (η5-Cp) Co (η4-C4Ph4) and its derivatives

D Kumar, M Deb, J Singh, N Singh, K Keshav… - Coordination Chemistry …, 2016 - Elsevier
A comprehensive review on the synthesis, reactions and applications centered on the highly
stable and sterically hindered cobalt sandwich compound (η 5-Cp) Co (η 4-C 4 Ph 4) is …

Cyclometalated palladium pre-catalyst for N-alkylation of amines using alcohols and regioselective alkylation of sulfanilamide using aryl alcohols

R Mamidala, V Mukundam, K Dhanunjayarao… - Tetrahedron, 2017 - Elsevier
Simple pyrazole based palladacycle-phosphine with a high turnover has been developed
and applied for the N-alkylation of amines and sulfanilamide using alcohols as substrates by …

Palladacycles based on 8-aminoquinoline carboxamides of cobalt and iron sandwich compounds and a new method to α-alkylate Cp rings of metal sandwich …

J Singh, M Deb, AJ Elias - Organometallics, 2015 - ACS Publications
Reactions of {η5-C5H4 [C (O) Cl]} Co (η4-C4Ph4) and {η5-C5H4 [C (O) Cl]} Fe (η5-Cp) with
8-aminoquinoline resulted in cobalt and iron sandwich derived carboxamides. The reaction …

Selective Manipulation of Well‐Defined Trinuclear Pd (II)‐Complexes

S Das, J Buschermöhle, DW Zant… - … A European Journal, 2024 - Wiley Online Library
Several strategies are available to design well‐defined multimetallic molecular entities
bearing functional ligands. Substoichiometric exchange reactions in the coordination sphere …

C–H Activation in Primary 3-Phenylpropylamines: Synthesis of Seven-Membered Palladacycles through Orthometalation. Stoichiometric Preparation of …

R Frutos-Pedreno, E Garcia-Sanchez… - Inorganic …, 2016 - ACS Publications
The dimeric cyclometalated complexes [Pd2 {κ2 C, N-C6H4CH2CH2C (R)(Me) NH2-2} 2 (μ-
Cl) 2](R= Me (1a), H (1b)) are prepared by reacting 1, 1-dimethyl-3-phenylpropylammonium …

Functionalized 1,3‐Diaminotruxillic Acids by Pd‐Mediated C–H Activation and [2+2]‐Photocycloaddition of 5(4H)‐Oxazolones

C Carrera, A Denisi, C Cativiela… - European Journal of …, 2019 - Wiley Online Library
The orthopalladation of (Z)‐4‐arylidene‐5 (4H)‐oxazolones (1a–1o), with electron‐
withdrawing substituents (Cl, F, CF3) in the 4‐arylidene ring has been carried out by C–H …

Preparation and characterization of cyclopalladated complexes derived from l-(−)-fenchone

GC Dickmu, IP Smoliakova - Journal of Organometallic Chemistry, 2014 - Elsevier
Abstract l-(−)-Fenchone 4 was reacted with RONH 2· HCl (R= H or Me) and pyridine in
ethanol to give l-fenchone oxime 5a and the corresponding O-methyl derivative 5b in 64 and …

Synthesis and Characterization of the Complete Series [(C5H5‐n Cln)Co(C4Ph4)] (n=1–5)

C Klein‐Heßling, K Sünkel - ChemistrySelect, 2021 - Wiley Online Library
Reflux of a mixture of [CoCl (PPh3) 3], Tl (C5H4Cl) and PhCCPh in toluene gave [(C5H4Cl)
Co (C4Ph4)] in ca. 20% yield. Deprotonation of this compound by lithium …

[PDF][PDF] The synthesis, catalytic investigation, and theoretical rationalisation of unsymmetrical pincer palladacycles

GW Roffe - 2016 - core.ac.uk
This thesis presents the synthesis of a number of unsymmetrical SCN, N'CN, PCN and PCS
pincer palladacycles. A new synthetic route has been designed towards unsymmetrical …

Reactions of Cp2TiMe2 with ferrocene and (ɳ5-Cp) Co (ɳ4-C4Ph4) derived esters and amides: A new route for 1-methylvinyl and methyl ketone derived metal …

J Singh, S Ghosh, M Deb, AJ Elias - Journal of Organometallic Chemistry, 2016 - Elsevier
Abstract Reactions of Cp 2 TiMe 2, with the ester derivatives of organometallic sandwich
compounds (ɳ 5-RC 5 H 4) Fe (ɳ 5-C 5 H 5) and (ɳ 5-RC 5 H 4) Co (ɳ 4-C 4 Ph 4)(R= ester …