Recent advances in oxidation catalysis using ionic liquids as solvents

D Betz, P Altmann, M Cokoja, WA Herrmann… - Coordination Chemistry …, 2011 - Elsevier
Ionic liquids are an interesting alternative to classical solvents presenting several
advantages. A variety of catalysts show good or even enhanced activities when applied in …

cis-Dioxo-molybdenum (VI) Schiff base complexes: synthesis, crystal structure and catalytic performance for homogeneous oxidation of olefins

S Rayati, N Rafiee, A Wojtczak - Inorganica Chimica Acta, 2012 - Elsevier
The synthesis of two Mo (VI) tetradentate Schiff base complexes derived from 2, 2′-
dimethylpropylenediamine and aromatic aldehydes,(MoO2 {hnaphnptn}(1) and MoO2 …

Molybdenum (VI) dioxo complexes employing Schiff base ligands with an intramolecular donor for highly selective olefin epoxidation

ME Judmaier, C Holzer, M Volpe… - Inorganic …, 2012 - ACS Publications
Reaction of [MoO2 (η2-t Bu2pz) 2] with Schiff base ligands HLX (X= 1–5) gave molybdenum
(VI) dioxo complexes of the type cis-[MoO2 (LX) 2] as yellow to light brown solids in …

An overview of chiral molybdenum complexes applied in enantioselective catalysis

JA Brito, B Royo, M Gomez - Catalysis Science & Technology, 2011 - pubs.rsc.org
The aim of this contribution is to highlight the attractive applications of molybdenum in
asymmetric catalysis. Even if molybdenum plays several biological roles mainly in …

Synthesis, characterization and pronounced epoxidation activity of cis-dioxo-molybdenum (VI) tridentate Schiff base complexes using tert-butyl hydroperoxide

A Rezaeifard, I Sheikhshoaie, N Monadi, M Alipour - Polyhedron, 2010 - Elsevier
The synthesis and catalytic performance of novel cis-dioxo-Mo (VI) complexes containing
simple ONO tridentate Schiff base ligands in the epoxidation of various olefins using tert …

Olefin epoxidation with a new class of ansa-molybdenum catalysts in ionic liquids

D Betz, A Raith, M Cokoja, FE Kuhn - ChemSusChem, 2010 - mediatum.ub.tum.de
mediaTUM - Medien- und Publikationsserver mediaTUM Universitätsbibliothek Technische
Universität München Logo Benutzer: Gast Login de en Erweiterte Suche mediaTUM …

Photo-assisted O-atom transfer to monoterpenes with molecular oxygen and a dioxoMo (VI) complex immobilized on TiO2 nanotubes

H Martinez, AA Amaya, EA Paez-Mozo, F Martinez… - Catalysis Today, 2021 - Elsevier
Selective oxidation of terpenes is a key enabling route to produce value-added epoxides
from renewable raw materials. In the present work, the photo-assisted oxygen atom transfer …

Molybdenum (VI) amino triphenolate complexes as catalysts for sulfoxidation, epoxidation and haloperoxidation

F Romano, A Linden, M Mba, C Zonta… - Advanced Synthesis & …, 2010 - Wiley Online Library
Two molybdenum (VI) complexes bearing a C3 symmetrical amino tris‐tert‐butylphenolate
ligand have proved to be air‐and water‐tolerant catalysts that efficiently catalyse, in high …

Photo-assisted selective oxidation of monoterpenes by a covalently supported dioxo-molybdenum complex on TiO2: Effect of electron donor ligands

H Martínez, ÁA Amaya, E Páez-Mozo, F Martínez - Molecular Catalysis, 2024 - Elsevier
High-valent dioxo-Mo species have demonstrated the ability to catalyze industrially
interesting alkene-to-epoxide transformations via oxygen atom transfer (OAT) reactions. The …

Aminothiazole Ligand-Type Dioxo-Mo(VI) Complex Anchored on TiO2 Nanotubes for Selective Oxidation of Monoterpenes with Light and O2

H Martinez Quiñonez, AA Amaya, EA Paez-Mozo… - Topics in …, 2022 - Springer
Abstract Selective Oxygen Atom Transfer to α-pinene, β-pinene,(R)-limonene and
camphene by dioxo-Mo (VI) Ln complex {Ln= 2-aminothiazole-4-carboxylic acid} anchored …