Measuring the Exciton Binding Energy: Learning from a Decade of Measurements on Halide Perovskites and Transition Metal Dichalcogenides

KR Hansen, JS Colton… - Advanced Optical …, 2024 - Wiley Online Library
The exciton binding energy (Eb) is a key parameter that governs the physics of many
optoelectronic devices. At their best, trustworthy and precise measurements of Eb challenge …

The origin of broad emission in⟨ 100⟩ two-dimensional perovskites: Extrinsic vs intrinsic processes

S Kahmann, D Meggiolaro, L Gregori… - ACS Energy …, 2022 - ACS Publications
2D metal halide perovskites can show narrow and broad emission bands (BEs), and the
latter's origin is hotly debated. A widespread opinion assigns BEs to the recombination of …

Emerging doping strategies in two-dimensional hybrid perovskite semiconductors for cutting edge optoelectronics applications

S Parveen, PK Giri - Nanoscale Advances, 2022 - pubs.rsc.org
The past decade has witnessed tremendous progress in metal halide perovskites,
particularly in lead (Pb) halide perovskites, because of their extraordinary performance in …

Revealing the crystallization and thermal-induced phase evolution in aromatic-based quasi-2D perovskites using a robot-based platform

J Zhang, J Wu, Y Zhao, Y Zou, A Barabash… - ACS Energy …, 2023 - ACS Publications
Introducing large organic cations to form reduced-dimensional (quasi-2D) perovskites has
proven to be effective in stabilizing three-dimensional perovskites. In this study, we …

Robust excitonic light emission in 2D tin halide perovskites by weak excited state polaronic effect

H Zhou, Q Feng, C Sun, Y Li, W Tao, W Tang… - Nature …, 2024 - nature.com
Abstract 2D perovskites hold immense promise in optoelectronics due to their strongly
bound electron-hole pairs (ie, excitons). While exciton polaron from interplay between …

Polaron vibronic progression shapes the optical response of 2D perovskites

M Dyksik, D Beret, M Baranowski, H Duim… - Advanced …, 2024 - Wiley Online Library
The optical response of 2D layered perovskites is composed of multiple equally‐spaced
spectral features, often interpreted as phonon replicas, separated by an energy Δ≃ 12− 40 …

Tailoring the high-brightness “warm” white light emission of two-dimensional perovskite crystals via a pressure-inhibited nonradiative transition

Y Fang, J Wang, L Zhang, G Niu, L Sui, G Wu… - Chemical …, 2023 - pubs.rsc.org
Efficient warm white light emission is an ideal characteristic of single-component materials
for light-emitting applications. Although two-dimensional hybrid perovskites are promising …

Low exciton binding energies and localized exciton–polaron states in 2D tin halide perovskites

KR Hansen, CE McClure, D Powell… - Advanced Optical …, 2022 - Wiley Online Library
Aside from band gap reduction, little is understood about the effect of the tin‐for‐lead
substitution on the fundamental optical and optoelectronic properties of metal halide …

Coherent Spin Dynamics of Electrons in Two-Dimensional (PEA)2PbI4 Perovskites

E Kirstein, EA Zhukov, DR Yakovlev, NE Kopteva… - Nano Letters, 2022 - ACS Publications
The versatile potential of lead halide perovskites and two-dimensional materials is merged
in the Ruddlesden–Popper perovskites having outstanding optical properties. Here, the …

Spin‐Flip Raman Scattering on Electrons and Holes in Two‐Dimensional (PEA)2PbI4 Perovskites

C Harkort, D Kudlacik, NE Kopteva, DR Yakovlev… - Small, 2023 - Wiley Online Library
Abstract The class of Ruddlesden–Popper type (PEA) 2PbI4 perovskites comprises 2D
structures whose optical properties are determined by excitons with a large binding energy …