Practical aerobic oxidations of alcohols and amines with homogeneous copper/TEMPO and related catalyst systems
BL Ryland, SS Stahl - Angewandte Chemie International …, 2014 - Wiley Online Library
Oxidations of alcohols and amines are common reactions in the synthesis of organic
molecules in the laboratory and industry. Aerobic oxidation methods have long been sought …
molecules in the laboratory and industry. Aerobic oxidation methods have long been sought …
Recent advances in the synthesis of aryl nitrile compounds
G Yan, Y Zhang, J Wang - Advanced Synthesis & Catalysis, 2017 - Wiley Online Library
Aryl nitriles are widely found in natural products, pharmaceuticals, agrochemicals, dyes, and
herbicides. Moreover, because the cyano group can be easily converted into various …
herbicides. Moreover, because the cyano group can be easily converted into various …
Efficient iron single-atom catalysts for selective ammoxidation of alcohols to nitriles
K Sun, H Shan, H Neumann, GP Lu, M Beller - Nature Communications, 2022 - nature.com
Zeolitic imidazolate frameworks derived Fe1-NC catalysts with isolated single iron atoms
have been synthesized and applied for selective ammoxidation reactions. For the …
have been synthesized and applied for selective ammoxidation reactions. For the …
Aerobic oxidation catalysis with stable radicals
Selective oxidation reactions are challenging when carried out on an industrial scale. Many
traditional methods are undesirable from an environmental or safety point of view. There is a …
traditional methods are undesirable from an environmental or safety point of view. There is a …
A sustainable multicomponent pyrimidine synthesis
N Deibl, K Ament, R Kempe - Journal of the American Chemical …, 2015 - ACS Publications
Since alcohols are accessible from indigestible biomass (lignocellulose), the development
of novel preferentially catalytic reactions in which alcohols are converted into important …
of novel preferentially catalytic reactions in which alcohols are converted into important …
TEMPO in chemical transformations: from homogeneous to heterogeneous
HA Beejapur, Q Zhang, K Hu, L Zhu, J Wang… - ACS Catalysis, 2019 - ACS Publications
The organic nitroxyl radical, TEMPO (2, 2, 6, 6-tetramethylpiperidine-N-oxyl), finds a variety
of industrial applications for chemical transformations. Because of economic and …
of industrial applications for chemical transformations. Because of economic and …
Green synthesis of nitriles using non-noble metal oxides-based nanocatalysts
RV Jagadeesh, H Junge, M Beller - Nature Communications, 2014 - nature.com
Abstract (Hetero) aromatic and aliphatic nitriles constitute major building blocks for organic
synthesis and represent a versatile motif found in numerous medicinally and biologically …
synthesis and represent a versatile motif found in numerous medicinally and biologically …
Organonitrogen chemicals from oxygen-containing feedstock over heterogeneous catalysts
Organonitrogen chemicals, such as amines, nitriles, amides, amino acids, and N-
heterocycles, are ubiquitous building blocks in chemical industry. Conventional …
heterocycles, are ubiquitous building blocks in chemical industry. Conventional …
Copper/TEMPO-catalyzed aerobic alcohol oxidation: mechanistic assessment of different catalyst systems
Combinations of homogeneous Cu salts and 2, 2, 6, 6-tetramethylpiperidine-N-oxyl
(TEMPO) have emerged as practical and efficient catalysts for the aerobic oxidation of …
(TEMPO) have emerged as practical and efficient catalysts for the aerobic oxidation of …
Nanoarchitectonics of sulfonated boron nitride for catalytic synthesis of aromatic nitriles under mild conditions
The development of sustainable protocols for synthesis of aromatic nitriles from
corresponding alcohols using metal-free heterogenous catalysts is a challenging task. In this …
corresponding alcohols using metal-free heterogenous catalysts is a challenging task. In this …