Chiral configurations in cyclophosphazene chemistry

A Uslu, S Yeşilot - Coordination Chemistry Reviews, 2015 - Elsevier
The pentavalent phosphorus atoms in cyclophosphazenes (NPXY) n are tetra-coordinated
and their potential centers of chirality are analogous to those for tetrahedral carbon …

Phosphorus–nitrogen compounds part 27. Syntheses, structural characterizations, antimicrobial and cytotoxic activities, and DNA interactions of new phosphazenes …

H Akbaş, A Okumuş, Z Kılıç, T Hökelek, Y Süzen… - European Journal of …, 2013 - Elsevier
Abstract A number of partly (7–9) and fully (10a–12d, Scheme 1) substituted mono (4-
fluorobenzyl) spiro cyclotriphosphazenes was prepared. The structures of the compounds …

Syntheses, structural characterization and biological activities of spiro-ansa-spiro-cyclotriphosphazenes

NS Başterzi, SB Koçak, A Okumuş, Z Kılıç… - New Journal of …, 2015 - pubs.rsc.org
The replacement reactions of the Cl-atoms in partly substituted spiro-ansa-spiro-
cyclotriphosphazenes (7 and 8) with excess pyrrolidine, 4-(2-aminoethyl) morpholine, and 1 …

Phosphorus− nitrogen compounds. 21. syntheses, structural investigations, biological activities, and DNA interactions of new N/O spirocyclic phosphazene derivatives …

M Işıklan, N Asmafiliz, EE Ozalp, EE Ilter… - Inorganic …, 2010 - ACS Publications
The reactions of hexachlorocyclotriphosphazatriene, N3P3Cl6, with N/O-donor-type N-alkyl
(or aryl)-o-hydroxybenzylamines (1a− 1e) produce mono-(2a− 2e), di-(3a− 3d), and tri-(4a …

Phosphorus–nitrogen compounds. Part 36. Syntheses, Langmuir–Blodgett thin films and biological activities of spiro-bino-spiro trimeric phosphazenes

N Asmafiliz, Z Kılıç, M Civan, O Avcı… - New Journal of …, 2016 - pubs.rsc.org
The condensation reactions of hexachlorocyclotriphosphazene (N3P3Cl6, trimer) with the
symmetric N2N2 or N2O2 donor type tetradentate bulky ligands (1–4) gave partly substituted …

Phosphorus-nitrogen compounds. Part 44. The syntheses of N, N-spiro bridged cyclotriphosphazene derivatives with (4-fluorobenzyl) pendant arms: Structural and …

E Öztürk, A Okumuş, Z Kılıç, A Kılıç, H Kayalak… - Inorganica Chimica …, 2019 - Elsevier
Abstract Isopropylaminopentachlorocyclotriphospha…,(N 3 P 3 Cl 5 (NHCHMe 2)(1),
containing a P–NH group in the alkyl-chain, gives the NN-spirobridged …

Syntheses and structural characterizations of 2-pyridyl (N/O) spirocyclotriphosphazene derivatives

G Elmas - Phosphorus, Sulfur, and Silicon and the Related …, 2019 - Taylor & Francis
The Cl exchange reaction of hexachlorocyclotriphosphazene, N3P3Cl6 (1), with one
equimolar amount of sodium salt of N/O donor type bidentate ligand containing a 2-pyridyl …

Ring-closing metathesis reactions of terminal alkene-derived cyclic phosphazenes

D Kumar, N Singh, K Keshav, AJ Elias - Inorganic Chemistry, 2011 - ACS Publications
The first examples of ring-closing metathesis (RCM) reactions of a series of terminal alkene-
derived cyclic phosphazenes have been carried out. The tetrakis-, hexakis-, and octakis …

Phosphorus–nitrogen compounds: Part 31. Syntheses, structural and stereogenic properties, in vitro cytotoxic and antimicrobial activities, and DNA interactions of …

G Mutlu, G Elmas, Z Kılıç, T Hökelek, LY Koc… - Inorganica Chimica …, 2015 - Elsevier
Abstract Hexachlorocyclotriphosphazene, N 3 P 3 Cl 6, and
octachlorocyclotetraphosphazene, N 4 P 4 Cl 8, were reacted with K 2 N 2 O 2 salt of …

[HTML][HTML] Phosphorus–nitrogen compounds Part 55. Syntheses of 4-methoxybenzylspiro (N/N) cyclotriphosphazenes: chemical, structural and biological properties

N Güven Kuzey, R Cemaloğlu, M Yakut… - Research on Chemical …, 2021 - Springer
The N 3 P 3 ring of hexachlorocyclotriphosphazene, N 3 P 3 Cl 6 (1)(HCCP; trimer), was
used significantly as a scaffold for the syntheses of inorganic–organic-based hybrid …