The Scholl reaction as a powerful tool for synthesis of curved polycyclic aromatics
The past decade has witnessed remarkable success in the synthesis of curved polycyclic
aromatics through Scholl reactions which enable oxidative aryl–aryl coupling even in …
aromatics through Scholl reactions which enable oxidative aryl–aryl coupling even in …
Construction of heptagon‐containing molecular nanocarbons
Chaolumen, IA Stepek, KE Yamada… - Angewandte Chemie …, 2021 - Wiley Online Library
Molecular nanocarbons containing heptagonal rings have attracted increasing interest due
to their dynamic behavior, electronic properties, aromaticity, and solid‐state packing …
to their dynamic behavior, electronic properties, aromaticity, and solid‐state packing …
[HTML][HTML] Highly contorted superhelicene hits near-infrared circularly polarized luminescence
Herein we describe a novel superhelicene structure consisting of three hexa-peri-
hexabenzocoronene (HBC) units arranged in a helical geometry and creating two carbo [5] …
hexabenzocoronene (HBC) units arranged in a helical geometry and creating two carbo [5] …
Azulene‐Fused Acenes
Non‐alternant non‐benzenoid π‐conjugated polycyclic hydrocarbons (PHs) are expected to
exhibit very different electronic properties from the all‐benzenoid PHs. Herein, we report the …
exhibit very different electronic properties from the all‐benzenoid PHs. Herein, we report the …
Perylene diimide-embedded double [8] helicenes
B Liu, M Böckmann, W Jiang… - Journal of the …, 2020 - ACS Publications
The rational design and modification of the helix is of significance for fully promoting
properties of configurationally stable materials for various applications in chiral science …
properties of configurationally stable materials for various applications in chiral science …
Synthesis of a Dicyclohepta[a,g]heptalene‐Containing Polycyclic Conjugated Hydrocarbon and the Impact of Non‐Alternant Topologies
J Wang, FG Gámez, J Marín‐Beloqui… - Angewandte …, 2023 - Wiley Online Library
Incorporating non‐hexagonal rings into polycyclic conjugated hydrocarbons (PCHs) can
significantly affect their electronic and optoelectronic properties and chemical reactivities …
significantly affect their electronic and optoelectronic properties and chemical reactivities …
Breathing new life into nonalternant hydrocarbon chemistry: Syntheses and properties of polycyclic hydrocarbons containing azulene, pentalene, and heptalene …
A Konishi, M Yasuda - Chemistry Letters, 2021 - academic.oup.com
Abstract Azulene 1, pentalene 2, and heptalene 3 are classical nonalternant hydrocarbons.
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …
Synthesis of defective nanographenes containing joined pentagons and heptagons
Y Fei, J Liu - Advanced Science, 2022 - Wiley Online Library
Defective nanographenes containing joined pentagons and heptagons exhibit striking
physicochemical properties from both experimental and theoretical perspectives compared …
physicochemical properties from both experimental and theoretical perspectives compared …
Synthesis of highly luminescent chiral nanographene
JK Li, XY Chen, WL Zhao, YL Guo… - Angewandte Chemie …, 2023 - Wiley Online Library
Chiral nanographenes with both high fluorescence quantum yields (ΦF) and large
dissymmetry factors (glum) are essential to the development of circularly polarized …
dissymmetry factors (glum) are essential to the development of circularly polarized …
Azulene‐Embedded [n]Helicenes (n=5, 6 and 7)
C Duan, J Zhang, J Xiang, X Yang… - Angewandte Chemie …, 2022 - Wiley Online Library
Azulene is a non‐benzenoid aromatic building block with unique chemical structure and
physicochemical properties. By using the “bottom‐up” synthetic strategy, we synthesized …
physicochemical properties. By using the “bottom‐up” synthetic strategy, we synthesized …