In mixed-valence (MV) systems essentially identical, more or less electronically coupled,
redox centres are brought into formally different oxidation states by removal or addition of an …

The concept of a molecular-based electronic technology has been evolving for over 50
years, and the development of molecular designs for such components over this period has …

This review is a cautionary note against the often purported direct relation between the half-
wave potential splitting Δ E 1/2 (or Δ E°) for stepwise, consecutive electron transfer from …

This review summarizes the electronic coupling studies in mixed-valence or donor–acceptor-
type complexes containing one or two cyclometalated ruthenium redox sites. Basic electron …

To streamline the interpretation of vibrational spectra, this work introduces the use of
Bayesian linear regression with automatic relevance determination as a viable approach to …

Oligo (arylene ethynylene)(OAE) derivatives are the “workhorse” molecules of molecular
electronics. Their ease of synthesis and flexibility of functionalisation mean that a diverse …

Coordination of the novel redox‐active phosphine‐appended aminophenol pincer ligand
(PNOH2) to PdII generates a paramagnetic complex with a persistent ligand‐centered …

Regio-and stereoselective insertion of the terminal ethynyl functions of 4-ethynylstilbene, the
E and Z isomers of 4, 4′-bis (ethynylphenyl) ethene and a backbone-rigidified cyclohexenyl …

The conformational energy landscape and the associated electronic structure and
spectroscopic properties (UV/Vis/near‐infrared (NIR) and IR) of three formally d5/d6 mixed …

Mixed‐valence compounds with the iso‐cyanidometal‐ligand bridge in different oxidation
states are used as models for the investigation of the electron‐transfer process. We …