Catalytic reactions that enable the formation of new bonds to carbon centres play a
pervasive role in the state-of-the-art synthesis of organic molecules and macromolecules. In …

The field of amine borane chemistry has seen significant advances and fascinating
developments in the last decade, mostly driven by the potential use of hydrogen-rich amine …

The following article is based on the MRS Medal talk presented by William L. Johnson at the
1998 MRS Fall Meeting on December 2, 1998. The MRS Medal is awarded for a specific …

Fluorobenzenes, in particular fluorobenzene (FB) and 1, 2-difluorobenzene (1, 2-DiFB), are
increasingly becoming recognised as versatile solvents for conducting organometallic …

A detailed catalytic, stoichiometric, and mechanistic study on the dehydrocoupling of H3B·
NMe2H and dehydropolymerization of H3B· NMeH2 using the [Rh (Xantphos)]+ fragment is …

Mechanistic studies into the catalysed dehydrocoupling of amine–boranes and phosphine–
boranes have seen a rapid development over the last 5 years. The primary driver for this …

Mild thermolysis of Lewis base stabilized phosphinoborane monomers R1R2P BH2⋅
NMe3 (R1, R2= H, Ph, or tBu/H) at room temperature to 100° C provides a convenient new …

Iron‐Catalyzed Dehydropolymerization: A Convenient Route to Poly(phosphinoboranes) with
Molecular‐Weight Control - Schäfer - 2015 - Angewandte Chemie International Edition - Wiley …

Catalytic dehydrocoupling/dehydrogenation of amine–borane adducts has become a field of
rapid growth over the past decade.[1] This development has been driven by potential …

The development of a simple, transition-metal-free approach for the formation of phosphorus–
phosphorus bonds through dehydrocoupling of phosphines is presented. The reaction is …