Carbon deposit analysis in catalyst deactivation, regeneration, and rejuvenation

ETC Vogt, D Fu, BM Weckhuysen - … Chemie International Edition, 2023 - Wiley Online Library
Hydrocarbon conversion catalysts suffer from deactivation by deposition or formation of
carbon deposits. Carbon deposit formation is thermodynamically favored above 350° C …

Preserved in a shell: high‐performance graphene‐confined ruthenium nanoparticles in acetylene hydrochlorination

SK Kaiser, R Lin, F Krumeich… - Angewandte Chemie …, 2019 - Wiley Online Library
The potential implementation of ruthenium‐based catalysts in polyvinyl chloride production
via acetylene hydrochlorination is hindered by their inferior activity and stability compared to …

Hydrogen production from homocyclic liquid organic hydrogen carriers (LOHCs): Benchmarking studies and energy-economic analyses

Y Kwak, J Kirk, S Moon, T Ohm, YJ Lee, M Jang… - Energy Conversion and …, 2021 - Elsevier
The construction of a cost-effective hydrogen infrastructure is needed to perpetuate the
deployment of the hydrogen economy. Liquid organic hydrogen carriers (LOHCs), generally …

Raman spectroscopy characterization of amorphous coke generated in industrial processes

CC Zhang, S Hartlaub, I Petrovic, B Yilmaz - ACS omega, 2022 - ACS Publications
Examples on the real-world field application of Raman spectroscopy with systematic
analysis of the intensity variation of D and G bands corresponding to the change of …

[HTML][HTML] A simultaneous depolymerization and hydrodeoxygenation process to produce lignin-based jet fuel in continuous flow reactor

A Kumar, DC Bell, Z Yang, J Heyne, DM Santosa… - Fuel Processing …, 2024 - Elsevier
Economical production of lignin-based jet fuel (LJF) can improve the sustainability of
sustainable aviation fuels (SAFs) as well as can reduce the overall greenhouse gas …

[HTML][HTML] Merits of the CeLaCuO ternary oxide as promoter of the Ni/SBA-15 catalyst for the dry reforming of methane reaction

AGS Hussien, AA Dabbawala, DH Anjum… - Chemical Engineering …, 2024 - Elsevier
This work reports on the catalytic performance of 5 wt% Ni/SBA-15 catalysts promoted with
different contents of CeLa10Cu metal-oxide (X= 0%, 10%, 20%, 30%, 40%) towards dry …

Direct analysis at temporal and molecular level of deactivating coke species formed on zeolite catalysts with diverse pore topologies

I Hita, HO Mohamed, Y Attada, N Zambrano… - Catalysis Science & …, 2023 - pubs.rsc.org
The mechanistic understanding of coke formation on zeolites is elusive, given the limitations
for the extraction and analysis of coke species. Here, we analyze the evolution of …

Rigorous Oxidation State Assignments for Supported Ga-Containing Catalysts Using Theory-Informed X-Ray Absorption Spectroscopy Signatures from Well-Defined …

L Li, JA Chalmers, SR Bare, SL Scott, FD Vila - ACS Catalysis, 2023 - ACS Publications
Gallium-based heterogeneous catalysts originally developed for commercial use in propane
dehydroaromatization have been explored extensively as potential replacements for Pt-and …

Molecular Structure–Reactivity Relationships for Olefin Metathesis by Al2O3-Supported Surface MoOx Sites

A Chakrabarti, IE Wachs - ACS Catalysis, 2018 - ACS Publications
Supported MoO x/Al2O3 catalysts were synthesized by incipient-wetness impregnation of
aqueous ammonium heptamolybdate, dried at room temperature and 110° C, and finally …

Nanoscale Chemical Diversity of Coke Deposits on Nanoprinted Metal Catalysts Visualized by Tip‐Enhanced Raman Spectroscopy

M Filez, P Walke, H Le‐The, S Toyouchi… - Advanced …, 2024 - Wiley Online Library
Coke formation is the prime cause of catalyst deactivation, where undesired carbon wastes
block the catalyst surface and hinder further reaction in a broad gamut of industrial chemical …