The metal-catalyzed carbenoid-based N–H insertions of α-stabilized diazo compounds and
relative precursors serve as robust strategies for the formation of C–N bonds. However …

Given the prevalence of heterocyclic scaffolds in drug‐related molecules, converting these
highly modular heterocyclic scaffolds into structural diversified and dearomatized analogs is …

Easy access to divergent products with chemoselectivity is of great importance in organic
synthesis. Herein, we have developed a chemoselective copper‐catalyzed carbene …

The first insertion of an alkynyl carbene into N–H bonds under Rh-catalysis is developed.
Alkynyl hydrazone carboxylates are used as donor–acceptor carbene precursors and are …

Paired electrolysis is an energy-efficient electrochemical reaction where both anodic and
cathodic electron flow directly induces product formation with maximum faradaic efficiency …

Despite the recent flurry of silver catalysis in modern synthetic organic chemistry, silver-
catalyzed carbene insertion into the N–H bonds remain scarce and limited to electron-poor …

Here we describe a homocoupling reaction of arylboronic acid facilitated by silver
carbonate, which proceeds smoothly in MeOH even at ambient temperature. The reaction …

Most of the reactivities of donor–acceptor (D–A) singlet carbenes are similar to metal
carbenoids. However, the lone pair at the carbenoid carbon, coordinated with metal, is free …

Sigmatropic rearrangement reactions are of prime interest in the construction of small
complex molecules and find widespread application in drug discovery and natural product …