Photo‐iniferter RAFT polymerization

M Hartlieb - Macromolecular Rapid Communications, 2022 - Wiley Online Library
Light‐mediated polymerization techniques offer distinct advantages over polymerization
reactions fueled by thermal energy, such as high spatial and temporal control as well as the …

Role of external field in polymerization: mechanism and kinetics

YN Zhou, JJ Li, YY Wu, ZH Luo - Chemical reviews, 2020 - ACS Publications
The past decades have witnessed an increasing interest in developing advanced
polymerization techniques subjected to external fields. Various physical modulations, such …

Advances in polymerizations modulated by external stimuli

AM Doerr, JM Burroughs, SR Gitter, X Yang… - ACS …, 2020 - ACS Publications
Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …

Oxygen tolerant photopolymerization for ultralow volumes

J Yeow, R Chapman, J Xu, C Boyer - Polymer Chemistry, 2017 - pubs.rsc.org
A benchtop approach is developed for the synthesis of various polymeric architectures using
an aqueous Reversible Addition–Fragmentation chain Transfer (RAFT) photopolymerization …

Excitation dependence in photoiniferter polymerization

RW Hughes, ME Lott, JI Bowman… - ACS Macro …, 2022 - ACS Publications
We report on a fundamental feature of photoiniferter polymerizations mediated with
trithiocarbonates and xanthates. The polymerizations were found to be highly dependent on …

Photocontrolled living polymerization systems with reversible deactivations through electron and energy transfer

S Shanmugam, J Xu, C Boyer - Macromolecular Rapid …, 2017 - Wiley Online Library
Recently, visible‐light‐regulated polymerization has been gaining popularity, as it opens a
range of new opportunities for the synthesis of functional polymers and materials. Here, the …

Ultrasonication-induced aqueous atom transfer radical polymerization

Z Wang, Z Wang, X Pan, L Fu, S Lathwal… - ACS Macro …, 2018 - ACS Publications
A new procedure for ultrasonication-induced atom transfer radical polymerization (sono-
ATRP) in aqueous media was developed. Polymerizations of oligo (ethylene oxide) methyl …

Photoregulated reversible addition–fragmentation chain transfer (RAFT) polymerization

S Li, G Han, W Zhang - Polymer Chemistry, 2020 - pubs.rsc.org
The past two decades have witnessed the significant progress of regulated reversible
addition–fragmentation chain transfer (RAFT) polymerization, and different strategies …

Photoinduced oxygen reduction for dark polymerization

S Shanmugam, J Xu, C Boyer - Macromolecules, 2017 - ACS Publications
Photopolymerization systems for controlled/living radical polymerization (CLRP) have often
been dependent on continuous irradiation to sustain radical production. Although this …

Reversible-addition fragmentation chain transfer (RAFT) mediated depolymerization of brush polymers

MJ Flanders, WM Gramlich - Polymer Chemistry, 2018 - pubs.rsc.org
Brush polymers synthesized by reversible-addition fragmentation chain transfer (RAFT)
polymerization underwent depolymerization when heated in the absence of initiator. The …