Innovative molecular design strategies in materials science following the aurophilicity concept
The past decade has seen a diverse range of breakthrough inventions that are derived from
gold complexes, including the application of aurophilic interactions in the preparation of …
gold complexes, including the application of aurophilic interactions in the preparation of …
Dinuclear gold (i) complexes: from bonding to applications
TACA Bayrakdar, T Scattolin, X Ma… - Chemical Society …, 2020 - pubs.rsc.org
The last two decades have seen a veritable explosion in the use of gold (I) complexes
bearing N-heterocyclic carbene (NHC) and phosphine (PR3) ligands. Both ligand families …
bearing N-heterocyclic carbene (NHC) and phosphine (PR3) ligands. Both ligand families …
Keep it tight: a crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes
AV Paderina, IO Koshevoy, EV Grachova - Dalton Transactions, 2021 - pubs.rsc.org
Copper subgroup metal ions in the+ 1 oxidation state are classical candidates for
aggregation via non-covalent metal–metal interactions, which are supported by a number of …
aggregation via non-covalent metal–metal interactions, which are supported by a number of …
Selective coordination of coinage metals using orthogonal ligand scaffolds
Group 11 metal complexes with their ability to form metallophilic interations are widely
pursued to develop multifunctional luminescent materials. Heteronuclear coinage metal …
pursued to develop multifunctional luminescent materials. Heteronuclear coinage metal …
Metallophilicity-induced clusterization: single-component white-light clusteroluminescence with stimulus response
Materials showing metallophilic interactions continue to attract considerable theoretical and
experimental attention largely because of their unusual and unanticipated photophysical …
experimental attention largely because of their unusual and unanticipated photophysical …
Luminescent Anionic Cyclometalated Organoplatinum (II) Complexes with Terminal and Bridging Cyanide Ligand: Structural and Photophysical Properties
M Sadeghian, D Gómez de Segura… - Inorganic …, 2023 - ACS Publications
We present the synthesis and characterization of two series of mononuclear heteroleptic
anionic cycloplatinated (II) complexes featuring terminal cyanide ligand Q+ [Pt (C^ N)(p …
anionic cycloplatinated (II) complexes featuring terminal cyanide ligand Q+ [Pt (C^ N)(p …
Au··· I coinage bonds: Boosting photoluminescence efficiency and solid‐state molecular motion
Coinage bonds, a type of noncovalent interaction, occur between group 11 elements (Au,
Ag, and Cu) with electron donor groups. Despite theoretical validation, empirical evidence …
Ag, and Cu) with electron donor groups. Despite theoretical validation, empirical evidence …
Is dual emission of copper subgroup d10-metal complexes a necessary and sufficient condition for ratiometric luminescence thermometry?
ID Strelnik, IE Kolesnikov, AA Kalinichev… - Mendeleev …, 2024 - Elsevier
Transition metal complexes of copper subgroup metals are actively studied objects for
temperature sensors. Their luminescence arising from the 3 ILCT, 3 MLCT or 3 CC excited …
temperature sensors. Their luminescence arising from the 3 ILCT, 3 MLCT or 3 CC excited …
A photoluminescent Au (I)/Ag (I)/PNN coordination complex for relatively rapid and reversible alcohol sensing
Y Tao, Y Wang, S Hu, DJ Young, C Lu, HX Li… - Dalton …, 2021 - pubs.rsc.org
Trinuclear complex [Au2Ag (dppmaphen) 2 (CN) 2] PF6 photoluminesces on exposure to
low molecular weight alcohols. This emission is likely due to C–H⋯ π interactions between …
low molecular weight alcohols. This emission is likely due to C–H⋯ π interactions between …
Porous Supramolecular Assembly of Pentiptycene-Containing Gold (I) Complexes: Persistent Excited-State Aurophilicity and Inclusion-Induced Emission …
YF Hsu, TW Wu, YH Kang, CY Wu, YH Liu… - Inorganic …, 2022 - ACS Publications
We report herein a porous supramolecular framework formed by a linear mononuclear Au (I)
complex (1) via the tongue-and-groove-like joinery between the pentiptycene U-cavities …
complex (1) via the tongue-and-groove-like joinery between the pentiptycene U-cavities …