Innovative molecular design strategies in materials science following the aurophilicity concept

N Mirzadeh, SH Privér, AJ Blake, H Schmidbaur… - Chemical …, 2020 - ACS Publications
The past decade has seen a diverse range of breakthrough inventions that are derived from
gold complexes, including the application of aurophilic interactions in the preparation of …

Dinuclear gold (i) complexes: from bonding to applications

TACA Bayrakdar, T Scattolin, X Ma… - Chemical Society …, 2020 - pubs.rsc.org
The last two decades have seen a veritable explosion in the use of gold (I) complexes
bearing N-heterocyclic carbene (NHC) and phosphine (PR3) ligands. Both ligand families …

Keep it tight: a crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes

AV Paderina, IO Koshevoy, EV Grachova - Dalton Transactions, 2021 - pubs.rsc.org
Copper subgroup metal ions in the+ 1 oxidation state are classical candidates for
aggregation via non-covalent metal–metal interactions, which are supported by a number of …

Selective coordination of coinage metals using orthogonal ligand scaffolds

VR Naina, F Krätschmer, PW Roesky - Chemical Communications, 2022 - pubs.rsc.org
Group 11 metal complexes with their ability to form metallophilic interations are widely
pursued to develop multifunctional luminescent materials. Heteronuclear coinage metal …

Metallophilicity-induced clusterization: single-component white-light clusteroluminescence with stimulus response

X Zhao, P Alam, J Zhang, S Lin, Q Peng… - CCS …, 2022 - chinesechemsoc.org
Materials showing metallophilic interactions continue to attract considerable theoretical and
experimental attention largely because of their unusual and unanticipated photophysical …

Luminescent Anionic Cyclometalated Organoplatinum (II) Complexes with Terminal and Bridging Cyanide Ligand: Structural and Photophysical Properties

M Sadeghian, D Gómez de Segura… - Inorganic …, 2023 - ACS Publications
We present the synthesis and characterization of two series of mononuclear heteroleptic
anionic cycloplatinated (II) complexes featuring terminal cyanide ligand Q+ [Pt (C^ N)(p …

Au··· I coinage bonds: Boosting photoluminescence efficiency and solid‐state molecular motion

X Zhao, J Gong, Z Li, HHY Sung, ID Williams… - …, 2024 - Wiley Online Library
Coinage bonds, a type of noncovalent interaction, occur between group 11 elements (Au,
Ag, and Cu) with electron donor groups. Despite theoretical validation, empirical evidence …

Is dual emission of copper subgroup d10-metal complexes a necessary and sufficient condition for ratiometric luminescence thermometry?

ID Strelnik, IE Kolesnikov, AA Kalinichev… - Mendeleev …, 2024 - Elsevier
Transition metal complexes of copper subgroup metals are actively studied objects for
temperature sensors. Their luminescence arising from the 3 ILCT, 3 MLCT or 3 CC excited …

A photoluminescent Au (I)/Ag (I)/PNN coordination complex for relatively rapid and reversible alcohol sensing

Y Tao, Y Wang, S Hu, DJ Young, C Lu, HX Li… - Dalton …, 2021 - pubs.rsc.org
Trinuclear complex [Au2Ag (dppmaphen) 2 (CN) 2] PF6 photoluminesces on exposure to
low molecular weight alcohols. This emission is likely due to C–H⋯ π interactions between …

Porous Supramolecular Assembly of Pentiptycene-Containing Gold (I) Complexes: Persistent Excited-State Aurophilicity and Inclusion-Induced Emission …

YF Hsu, TW Wu, YH Kang, CY Wu, YH Liu… - Inorganic …, 2022 - ACS Publications
We report herein a porous supramolecular framework formed by a linear mononuclear Au (I)
complex (1) via the tongue-and-groove-like joinery between the pentiptycene U-cavities …