Spin frustration in organic radicals
S Tang, X Wang - Angewandte Chemie International Edition, 2024 - Wiley Online Library
Spin frustration, which results from geometric frustration and a systematical inability to satisfy
all antiferromagnetic (AF) interactions between unpaired spins simultaneously, is under the …
all antiferromagnetic (AF) interactions between unpaired spins simultaneously, is under the …
Quantum spin liquids from a materials perspective
L Clark, AH Abdeldaim - Annual Review of Materials Research, 2021 - annualreviews.org
Quantum spin liquids are unique quantum states of matter predicted to arise in low-
dimensional, frustrated, and quantum magnetic systems. Compared with conventional …
dimensional, frustrated, and quantum magnetic systems. Compared with conventional …
Spin-frustrated trisradical trication of prismcage
Organic trisradicals featuring threefold symmetry have attracted significant interest because
of their unique magnetic properties associated with spin frustration. Herein, we describe the …
of their unique magnetic properties associated with spin frustration. Herein, we describe the …
Planar, curved and twisted molecular nanographenes: Reduction-induced alkali metal coordination
Z Zhou, MA Petrukhina - Coordination Chemistry Reviews, 2023 - Elsevier
Planar and curved polycyclic aromatic hydrocarbons (PAHs) attract significant attention as
molecular models of fullerenes, carbon nanotubes, and graphene, thus stimulating broad …
molecular models of fullerenes, carbon nanotubes, and graphene, thus stimulating broad …
Topology-Dependent Synthesis, Structures, and Bonding Interactions of Uranium Polyarene Complexes
C Deng, XC Xu, R Sun, Y Wang, BW Wang… - …, 2024 - ACS Publications
Metal polyarene complexes have attracted great attention in recent years because of their
appealing electronic structures and readily tunable properties and reactivity. While main …
appealing electronic structures and readily tunable properties and reactivity. While main …
Tuning magnetic interactions between triphenylene radicals by variation of crystal packing in structures with alkali metal counterions
The monoanion of triphenylene (C18H12, 1) was generated in THF using several alkali
metals (Na, K, Rb, and Cs) as reducing agents and crystallized with the corresponding …
metals (Na, K, Rb, and Cs) as reducing agents and crystallized with the corresponding …
Redox-controlled potassium intercalation into two polyaromatic hydrocarbon solids
Alkali metal intercalation into polyaromatic hydrocarbons (PAHs) has been studied intensely
after reports of superconductivity in a number of potassium-and rubidium-intercalated …
after reports of superconductivity in a number of potassium-and rubidium-intercalated …
Chemical modification toward long spin lifetimes in organic conjugated radicals
Organic semiconductors for spin‐based devices require long spin relaxation times.
Understanding their spin relaxation mechanisms is critical to organic spintronic devices and …
Understanding their spin relaxation mechanisms is critical to organic spintronic devices and …
Multiple Cation Insertion into a Polyaromatic Hydrocarbon Guided by Data and Computation
MJ Rosseinsky, M Dutta, AB Canaj, T Knaflič… - Chemical …, 2024 - pubs.rsc.org
We report the synthesis, structural characterization and magnetic properties of K3coronene,
and demonstrate a computational screening workflow designed to accelerate the discovery …
and demonstrate a computational screening workflow designed to accelerate the discovery …