Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and …

JA Rodriguez, DC Grinter, Z Liu… - Chemical Society …, 2017 - pubs.rsc.org
Model metal/ceria and ceria/metal catalysts have been shown to be excellent systems for
studying fundamental phenomena linked to the operation of technical catalysts. In the last …

Oxidation of reduced ceria by incorporation of hydrogen

Z Li, K Werner, K Qian, R You… - Angewandte Chemie …, 2019 - Wiley Online Library
The interaction of hydrogen with reduced ceria (CeO2− x) powders and CeO2− x (111) thin
films was studied using several characterization techniques including TEM, XRD, LEED …

Behavior of TiO2 and CeO2 Nanoparticles and Polystyrene Nanoplastics in Bottled Mineral, Drinking and Lake Geneva Waters. Impact of Water Hardness and …

L Ramirez, S Ramseier Gentile, S Zimmermann, S Stoll - Water, 2019 - mdpi.com
Intensive use of engineered nanoparticles (NPs) in daily products ineluctably results in their
release into aquatic systems and consequently into drinking water resources. Therefore …

Coagulation of TiO2, CeO2 nanoparticles, and polystyrene nanoplastics in bottled mineral and surface waters. Effect of water properties, coagulant type, and dosage

L Ramirez Arenas, S Ramseier Gentile… - Water Environment …, 2020 - Wiley Online Library
Intensive use of engineered nanoparticles (NPs) results in their release into aquatic systems
and consequently into drinking water resources. Therefore, it is important to evaluate how …

Ce=O Terminated CeO2

DC Grinter, M Allan, HJ Yang, A Salcedo… - Angewandte Chemie …, 2021 - Wiley Online Library
Multiply bonded lanthanide oxo groups are rare in coordination compounds and have not
previously been reported for a surface termination of a lanthanide oxide. Here we report the …

The cubic-to-hexagonal phase transition of cerium oxide particles: dynamics and structure

J Höcker, JO Krisponeit, T Schmidt, J Falta, JI Flege - Nanoscale, 2017 - pubs.rsc.org
Cerium oxide is often applied in today's catalysts due to its remarkable oxygen storage
capacity. The changes in stoichiometry during reaction are linked to structural modifications …

Facilitating role of Pd for hydrogen, oxygen and water adsorption/desorption processes from bulk CeO2 and CeO2/γ-Al2O3

D Kaya, D Singh, S Kincal, D Uner - Catalysis Today, 2019 - Elsevier
The enhanced rates of reduction and re-oxidation of ceria in the presence of Pd, was
investigated on both bulk ceria as well as ceria deposited over γ-Al 2 O 3. Pd addition and …

Probing Pt-CeO2 interfacial interactions through adsorption characteristics of small molecules

A Mohammadpour, S Kaya - Journal of Catalysis, 2024 - Elsevier
In this study, we prepared a Pt/CeO 2/Cu (1 1 1) model catalyst and investigated CO and CO
2 adsorption using infrared reflection absorption spectroscopy (IRRAS) and temperature …

Establishing structure-sensitivity of ceria reducibility: real-time observations of surface-hydrogen interactions

T Duchoň, J Hackl, DN Mueller, J Kullgren… - Journal of Materials …, 2020 - pubs.rsc.org
The first layer of atoms on an oxide catalyst provides the first sites for adsorption of reactants
and the last sites before products or oxygen are desorbed. We employ a unique combination …

[PDF][PDF] Fluorescence-detected XAS with sub-second time resolution reveals new details about the redox activity of Pt/CeO2 catalyst

AA Guda, AL Bugaev, R Kopelent… - Journal of …, 2018 - journals.iucr.org
A setup for fluorescence-detected X-ray absorption spectroscopy (XAS) with sub-second
time resolution has been developed. This technique allows chemical speciation of low …