Navigating the unnatural reaction space: directed evolution of heme proteins for selective carbene and nitrene transfer

Y Yang, FH Arnold - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Despite the astonishing diversity of naturally occurring biocatalytic processes,
enzymes do not catalyze many of the transformations favored by synthetic chemists. Either …

Towards Sustainable Oxalic Acid from CO2 and Biomass

E Schuler, M Demetriou, NR Shiju… - ChemSusChem, 2021 - Wiley Online Library
To quickly and drastically reduce CO2 emissions and meet our ambitions of a circular future,
we need to develop carbon capture and storage (CCS) and carbon capture and utilization …

Recent advances in intensified ethylene production—a review

Y Gao, L Neal, D Ding, W Wu, C Baroi, AM Gaffney… - ACS …, 2019 - ACS Publications
Steam cracking is a well-established commercial technology for ethylene production.
Despite decades of optimization efforts, the process is, nevertheless, highly energy and …

[图书][B] Modern oxidation methods

JE Bäckvall - 2011 - books.google.com
While rust is an unwanted oxidation reaction, there are also many other useful oxidation
reactions that are extremely important and number among the most commonly used …

Cytochromes P450 as versatile biocatalysts

R Bernhardt - Journal of biotechnology, 2006 - Elsevier
Cytochromes P450 are ubiquitously distributed enzymes, which were discovered about 50
years ago and which possess high complexity and display a broad field of activity. They are …

Tuning P450 enzymes as oxidation catalysts

R Fasan - Acs Catalysis, 2012 - ACS Publications
The development of catalytic systems for the controlled oxidation of C–H bonds remains a
highly sought-after goal in chemistry owing to the great utility of such transformation toward …

Enzymatic Hydroxylations of sp3-Carbons

J Munch, P Pullmann, W Zhang, MJ Weissenborn - Acs Catalysis, 2021 - ACS Publications
Enzymatic hydroxylation of activated and nonactivated sp3-carbons attracts keen interest
from the chemistry community as it is one of the most challenging tasks in organic synthesis …

Enzyme-mediated oxidations for the chemist

F Hollmann, IWCE Arends, K Buehler, A Schallmey… - Green …, 2011 - pubs.rsc.org
Biocatalysis is an enabling technology adding to organic oxidation chemistry. Especially the
high selectivity of enzymatic oxidation coevally operating under mild conditions and not …

High-rate solar-light photoconversion of CO 2 to fuel: controllable transformation from C 1 to C 2 products

S Sorcar, J Thompson, Y Hwang, YH Park… - Energy & …, 2018 - pubs.rsc.org
The production of solar fuels offers a viable pathway for reducing atmospheric CO2
concentrations and the storage and transport of solar energy. While photoconversion of CO2 …

Selective Catalytic Oxidation of C H Bonds with Molecular Oxygen

E Roduner, W Kaim, B Sarkar, VB Urlacher… - …, 2013 - Wiley Online Library
Although catalytic reductions, cross‐couplings, metathesis, and oxidation of C C double
bonds are well established, the corresponding catalytic hydroxylations of C H bonds in …