Fischer Carbene Complexes: A Glance at Two Decades of Research on Higher‐Order Cycloaddition Reactions

A Feliciano, JL Vázquez… - … A European Journal, 2021 - Wiley Online Library
The structure of Fischer carbene complexes (FCCs) is electron deficient. If bearing an α, β‐
unsaturated system, it can generate a wide variety of compounds by undergoing many …

Iridaaromatics via Methoxy (alkenyl) carbeneiridium Complexes

M Talavera, S Bolaño - Molecules, 2021 - mdpi.com
This review describes the development of a versatile methodology to synthesize polycyclic
metallaaromatic hydrocarbons based on iridium, as well as the studies that helped us to …

Metal Free Dötz‐Type Aminobenzannulation Reaction via 1, 1‐Dipoles Cross‐Coupling

W Cai, Y Huang - Angewandte Chemie International Edition, 2023 - Wiley Online Library
Aryl amines are of constant interest in organic synthesis owing to their ubiquity in natural
products, pharmaceuticals, and organic materials. However, C− H amination or pre …

Photoinduced Copper‐Catalyzed Cross‐Coupling of Acylsilanes with Heteroarenes via Bimetallic Relay

L Zheng, YC Li, Y Wu, P Wang - Advanced Science, 2024 - Wiley Online Library
The transition metal‐catalyzed direct coupling reactions involving electron‐rich Fischer
carbene species are largely underdeveloped and remain a big challenge. Here, a direct …

Photoinduced Copper-Catalyzed Cross-Coupling of Acylsilanes with Azoles

L Zheng, YC Li, Y Wu, P Wang - 2024 - chemrxiv.org
The transition metal-catalyzed direct coupling reac-tions involving electron-rich Fisher
carbene species are largely underdeveloped and remain a big chal-lenge. Here, we report a …