Hierarchical nanomaterials assembled from peptoids and other sequence-defined synthetic polymers
In nature, the self-assembly of sequence-specific biopolymers into hierarchical structures
plays an essential role in the construction of functional biomaterials. To develop synthetic …
plays an essential role in the construction of functional biomaterials. To develop synthetic …
The diverse world of foldamers: endless possibilities of self-assembly
S Rinaldi - Molecules, 2020 - mdpi.com
Different classes of foldamers, which are synthetic oligomers that adopt well-defined
conformations in solution, have been the subject of extensive studies devoted to the …
conformations in solution, have been the subject of extensive studies devoted to the …
Single-molecule polypeptoid stretching reveals the effects of charge sequence on chain conformation
Elucidating the effect of charge sequence on polyelectrolyte conformation is important to
understanding many biophysical processes and advancing the design of sequence-defined …
understanding many biophysical processes and advancing the design of sequence-defined …
Biomolecular assemblies: moving from observation to predictive design
CJ Wilson, AS Bommarius, JA Champion… - Chemical …, 2018 - ACS Publications
Biomolecular assembly is a key driving force in nearly all life processes, providing structure,
information storage, and communication within cells and at the whole organism level. These …
information storage, and communication within cells and at the whole organism level. These …
Supramolecular Nanosheets Assembled from Poly(ethylene glycol)-b-poly(N-(2-phenylethyl)glycine) Diblock Copolymer Containing Crystallizable Hydrophobic …
Y Wei, J Tian, Z Zhang, C Zhu, J Sun, Z Li - Macromolecules, 2019 - ACS Publications
Supramolecular two-dimensional (2D) nanomaterials from block copolymers have received
great interest for their unique structure and properties. Here, we report the formation of …
great interest for their unique structure and properties. Here, we report the formation of …
Structural elucidation of a polypeptoid chain in a crystalline lattice reveals key morphology-directing role of the N-terminus
The ability to engineer synthetic polymers with the same structural precision as
biomacromolecules is crucial to enable the de novo design of robust nanomaterials with …
biomacromolecules is crucial to enable the de novo design of robust nanomaterials with …
Conformations of peptoids in nanosheets result from the interplay of backbone energetics and intermolecular interactions
The conformations adopted by the molecular constituents of a supramolecular assembly
influence its large-scale order. At the same time, the interactions made in assemblies by …
influence its large-scale order. At the same time, the interactions made in assemblies by …
Control over conformational landscapes of polypeptoids by monomer sequence patterning
The ability to program chain conformation and structure through control over the monomer
sequence of synthetic polymers has broad implications for next-generation material design …
sequence of synthetic polymers has broad implications for next-generation material design …
2D Liquid-Crystallization-Driven Self-Assembly of Rod–Coil Block Copolymers: Living Growth and Self-Similarity
Liquid-crystallization-driven self-assembly (LCDSA) is an emerging methodology, which has
been employed to construct controllable 1D nanostructures. However, 2D nanostructures via …
been employed to construct controllable 1D nanostructures. However, 2D nanostructures via …
Engineering the atomic structure of sequence-defined peptoid polymers and their assemblies
S Xuan, RN Zuckermann - Polymer, 2020 - Elsevier
Peptoids are a family of sequence-defined, non-natural biomimetic polymers which show
excellent properties including good chemical and enzymatic stability and high structural …
excellent properties including good chemical and enzymatic stability and high structural …