Constraining molecules at the closest approach: chemistry at high pressure

V Schettino, R Bini - Chemical Society Reviews, 2007 - pubs.rsc.org
The purpose of this tutorial review is to illustrate the effects that the application of high
pressures can have on chemical reactions involving highly compressible molecular …

Chemistry of hydrocarbons under extreme thermobaric conditions

AY Kolesnikov, JM Saul, VG Kutcherov - ChemistrySelect, 2017 - Wiley Online Library
What will happen when methane is at a temperature of 1500 K? On the first glance the
answer seems to be obvious‐methane will decompose into hydrogen and one of the forms …

One-dimensional diamondoid polyaniline-like nanothreads from compressed crystal aniline

MM Nobrega, E Teixeira-Neto, AB Cairns… - Chemical …, 2018 - pubs.rsc.org
Low-dimensional nanomaterials such as highly ordered polyaniline (PANI) have attracted
considerable interest due to their expected extraordinary electronic and optoelectronic …

Structure determination of ζ-N2 from single-crystal X-ray diffraction and theoretical suggestion for the formation of amorphous nitrogen

D Laniel, F Trybel, A Aslandukov, J Spender… - Nature …, 2023 - nature.com
The allotropy of solid molecular nitrogen is the consequence of a complex interplay between
fundamental intermolecular as well as intramolecular interactions. Understanding the …

Pressure-induced polymerization of acrylic acid: a Raman spectroscopic study

C Murli, Y Song - The Journal of Physical Chemistry B, 2010 - ACS Publications
We report here the first in-situ Raman spectroscopic study of pressure-induced structural
and polymeric transformations of acrylic acid. Two crystalline phases (I and II) were …

Synthesis of double core chromophore-functionalized nanothreads by compressing azobenzene in a diamond anvil cell

S Romi, S Fanetti, F Alabarse, AM Mio, R Bini - Chemical science, 2021 - pubs.rsc.org
Carbon nanothreads are likely the most attracting new materials produced under high
pressure conditions. Their synthesis is achieved by compressing crystals of different small …

High-pressure synthesis of a polyethylene/zeolite nano-composite material

M Santoro, FA Gorelli, R Bini, J Haines… - Nature …, 2013 - nature.com
Meso/micro-porous solids, such as zeolites, are complex materials used in an impressive
range of applications. Here we photo-polymerized ethylene using non-catalytic high …

Insights into perovskite film formation using the hybrid evaporation/spin-coating route: an in situ XRD study

O Er-Raji, L Rustam, BP Kore, SW Glunz… - ACS Applied Energy …, 2023 - ACS Publications
The hybrid evaporation/spin-coating route has been widely used for fabrication of highly
efficient fully textured perovskite silicon tandem solar cells and is a promising route for …

High pressure polymerization in a confined space: conjugated chain/zeolite nanocomposites

D Scelta, M Ceppatelli, M Santoro, R Bini… - Chemistry of …, 2014 - ACS Publications
Conducting polymers are one of the most promising classes of materials for enabling
technologies such as solar energy conversion, organic electronics, and opto-electronics …

Synthesis of 1D polymer/zeolite nanocomposites under high pressure

M Santoro, D Scelta, K Dziubek, M Ceppatelli… - Chemistry of …, 2016 - ACS Publications
Recently, simple carbon based polymers have been synthesized at high pressures in
silicalite, a pure SiO2 zeolite with a 3D system of mutually interconnected microchannels …