Perfluoroorganosilver (I) compounds

W Tyrra, D Naumann - Journal of fluorine chemistry, 2004 - Elsevier
A survey of different methods to prepare perfluoroorganosilver (I) compounds is given. The
reaction of silver (I) fluoride with trimethyl (perfluoroorgano) silanes offers a new convenient …

M… π (arene) interactions for M= gallium, indium and thallium: Influence upon supramolecular self-assembly and prevalence in some proteins

I Caracelli, I Haiduc, J Zukerman-Schpector… - Coordination Chemistry …, 2014 - Elsevier
A bibliographic survey of the crystallographic literature reveals that Tl (lone pair)… π (arene)
interactions, where the lone pair of electrons is projected plumb to the centre of the arene …

Synthesis of pentafluorophenyl silver by means of Lewis acid catalysis: structure of silver solvent complexes

M Kuprat, M Lehmann, A Schulz, A Villinger - Organometallics, 2010 - ACS Publications
The synthesis and structure of lithium and silver tetrakis (pentafluorophenyl) borate salts
have been studied in different solvents ranging from polar (CH2Cl2, diethyl ether) to …

Stable mono-and dinuclear organosilver complexes

BK Tate, AJ Jordan, J Bacsa, JP Sadighi - Organometallics, 2017 - ACS Publications
A series of mononuclear and dinuclear complexes of silver (I), supported by an N-
heterocyclic carbene and bound to sp3-, sp2-, and sp-hybridized carbanions, has been …

Silver Compounds in Synthetic Chemistry. 1 A Facile Preparative Route for Pentafluorophenylsilver, AgC6F5 and its Use as an Oxidative Pentafluorophenyl Group Transfer Reagent in …

W Tyrra, MS Wickleder - Zeitschrift für anorganische und …, 2002 - Wiley Online Library
AgC6F5 is directly and quantitatively formed from room temperature reactions of AgF and
Me3SiC6F5 in N‐donor solvents, particularly EtCN. Solutions of AgC6F5 prepared by this …

Synthesis and Structural Characterization of Phosphanide Gold (III)/Gold (I) Complexes and Their Thallium (III) and Gold (III) Precursors

L Coconubo-Guio, JM López-de-Luzuriaga, S Moreno… - Molecules, 2023 - mdpi.com
In this paper, we describe a series of diphenylphosphane and diphenylphosphanide gold
(III) and gold (III)/gold (I) complexes containing 3, 5-C6Cl2F3 as aryl ligands at gold that …

Organometal fluorides of aluminium, gallium, indium and thallium

B Neumüller - Coordination chemistry reviews, 1997 - Elsevier
Diorganometal fluorides can be synthesized by reaction of the corresponding metallanes
with synthons like BF3 (OEt) 2 and Me3SnF. A second general synthesis strategy is the …

Structural aspects of the coordination chemistry of organothallium (III) and organomercury (II) derivatives

JS Casas, MS Garcıa-Tasende, J Sordo - Coordination Chemistry Reviews, 1999 - Elsevier
This review surveys the main structural aspects of the coordination chemistry of mono-, di-
and triorganothallium (III) and mono-and diorganomercury (II) complexes. It covers all …

Structural characterization of bis (pyrazolyl) hydroborato thallium complexes: monomeric “two-coordinate” thallium derivatives supplemented by [Tl… HB] interactions

C Dowling, P Ghosh, G Parkin - Polyhedron, 1997 - Elsevier
The syntheses and structural characterization of a series of mononuclear bis (pyrazolyl)
hydroborato thallium complexes Tl [BpButR](R= Me, Prii, But) are described. In each case …

Silver compounds in synthetic chemistry: Part 2: A convenient synthesis of 2, 3, 4, 5, 6-pentafluorophenones, C6F5COR, from pentafluorophenylsilver, AgC6F5, and …

MM Kremlev, W Tyrra, D Naumann… - Journal of fluorine …, 2005 - Elsevier
Silver compounds in synthetic chemistry: Part 2: A convenient synthesis of 2,3,4,5,6-pentafluorophenones,
C6F5COR, from pentafluorophenylsilver, AgC6F5, and the corresponding acid chlorides …