Mechanistic studies on single-electron transfer in frustrated Lewis pairs and its application to main-group chemistry

LJC van der Zee, J Hofman, JM van Gaalen… - Chemical Society …, 2024 - pubs.rsc.org
Advances in the field of frustrated Lewis pair (FLP) chemistry have led to the discovery of
radical pairs, obtained by a single-electron transfer (SET) from the Lewis base to the Lewis …

Radical reactions enabled by polyfluoroaryl fragments: photocatalysis and beyond

MO Zubkov, AD Dilman - Chemical Society Reviews, 2024 - pubs.rsc.org
Polyfluoroarenes have been known for a long time, but they are most often used as
fluorinated building blocks for the synthesis of aromatic compounds. At the same time, due to …

Light-Induced Polymeric Frustrated Radical Pairs as Building Blocks for Materials and Photocatalysts

M Wang, M Shanmugam, EJL McInnes… - Journal of the …, 2023 - ACS Publications
Polymeric frustrated Lewis pairs, or poly (FLP) s, have served to bridge the gap between
functional polymer science and main group catalysis, pairing the uniqueness of sterically …

Coordination-induced OH/NH bond weakening by a redox non-innocent, aluminum-containing radical

S Sinhababu, RP Singh, MR Radzhabov… - Nature …, 2024 - nature.com
Several renewable energy schemes aim to use the chemical bonds in abundant molecules
like water and ammonia as energy reservoirs. Because the OH and NH bonds are quite …

Sequential radical and cationic reactivity at separated sites within one molecule in solution

S Liu, Y Li, J Lin, Z Ke, H Grützmacher, CY Su, Z Li - Chemical Science, 2024 - pubs.rsc.org
Distonic radical cations (DRCs) with spatially separated charge and radical sites are
expected to show both radical and cationic reactivity at different sites within one molecule …

Synthesis and Photochemical Uncaging of Alkene-Protected, Polymer-Bound Vicinal Frustrated Lewis Pairs

EA Latif, JD Hilgar, NA Romero - Journal of the American …, 2024 - ACS Publications
Polymeric materials bearing Frustrated Lewis Pair (FLP) functionality are promising
candidates for use as heterogeneous catalysts and adaptive materials, but synthetic access …

Uncovering Factors Controlling Reactivity of Metal‐TEMPO Reaction Systems in the Solid State and Solution

K Budny‐Godlewski, DG Piekarski… - … A European Journal, 2024 - Wiley Online Library
Nitroxides find application in various areas of chemistry, and a more in‐depth understanding
of factors controlling their reactivity with metal complexes is warranted to promote further …

p-Diarylboryl Halothiophenols as Multifunctional Catalysts via Photoactive Intramolecular Frustrated Lewis Pairs

T Kikura, Y Taura, Y Aramaki, T Ooi - Journal of the American …, 2024 - ACS Publications
p-Diarylboryl halothiophenols are developed and unequivocally characterized. Their
photophysical properties and catalytic performance are unveiled by experimental and …

Coordination chemistry and FLP reactivity of 1, 1-and 1, 2-bis-boranes

A Yeganeh-Salman, J Yeung, L Miao… - Dalton Transactions, 2024 - pubs.rsc.org
Coordination chemistry and frustrated Lewis pair (FLP) chemistry have been most commonly
studied using monodentate Lewis acids. In this paper, we examine the corresponding …

B (C6F5) 3-catalyzed selective C–H chalcogenation of arenes and heteroarenes

M Pramanik, S Das, R Babaahmadi, S Pahar, T Wirth… - Chem, 2024 - cell.com
The synthesis of organochalcogenides remains a valuable area of research due to their
widespread biological applications, particularly in pharmaceuticals. Herein, our study details …